Triethanolamine as an inexpensive and efficient ligand for copper-catalyzed hydroxylation of aryl halides in water

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成果类型：

期刊论文

作者：

Wang, Deping*;Kuang, Daizhi;Zhang, Fuxing;Tang, Siping;Jiang, Wujiu

通讯作者：

Wang, Deping

作者机构：

[Tang, Siping; Jiang, Wujiu; Zhang, Fuxing; Wang, Deping; Kuang, Daizhi] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan Province, Peoples R China.

[Tang, Siping; Zhang, Fuxing; Wang, Deping; Kuang, Daizhi] Hengyang Normal Univ, Key Discipline Mat Phys & Chem, Five Year Plan Key Construct Disciplines Hunan Pr, Hengyang 421008, Hunan Province, Peoples R China.

[Wang, Deping] Hengyang Normal Univ, Dept Chem & Mat Sci, 165 Huangbai Rd, Hengyang 421008, Hunan Province, Peoples R China.

通讯机构：

[Wang, Deping] H

Hengyang Normal Univ, Dept Chem & Mat Sci, 165 Huangbai Rd, Hengyang 421008, Hunan Province, Peoples R China.

语种：

英文

关键词：

Copper;Hydroxylation;N ligands;Phenols;Water chemistry

期刊：

European Journal of Organic Chemistry

ISSN：

1434-193X

年：

2014

卷：

2014

期：

页码：

315-318

DOI：

10.1002/ejoc.201301370

基金类别：

National Natural Science Foundation of China (NSFC)National Natural Science Foundation of China (NSFC) [21202041, 21102040]; Scientific Research Foundation of Hengyang Normal University [11B39]

机构署名：

本校为第一且通讯机构

院系归属：

化学与材料科学学院

摘要：

The CuI/triethanolamine catalyst system efficiently promotes the direct hydroxylation of aryl iodides and bromides in water to provide the corresponding phenols in good to excellent yields. Moreover, the procedure avoids the use of toxic organic solvents and tol...

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Triethanolamine as an inexpensive and efficient ligand for copper-catalyzed hydroxylation of aryl halides in water

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