A novel tricyclohexyltin complex Cy3 SnOC9 NH6 was synthesized by the reaction of 8-quinolinol with tricyclohexyhin hydroxide under microwave irradiation, and characterized by UV, IR, 1^H and 13^C NMR, elemental analysis and X-ray crystal diffraction. The crystal belongs to triclinic system, space group P1-with the cell parameters:a =0. 99530(5) nm, b = 1. 01129(5) nm, c =2. 58327(13) nm, a = 89. 1880(10) o, = 86. 6290 (10)°, γ = 81. 2490 (10) °, Z = 4, V = 2. 5654 (2) nm^3, Dc = 1. 326 Mg/m^3, μ(MoKa) = 1.013 mm^-1, F(000...