The crystal structure of bis(p-chlorobenzyl) tin dichloride has been determined by X-ray diffraction method. The crystal belongs to monoclinic space group C2/c with a = 2.8010(3), b = 0.4882(2), c = 1.2174(3) nm, β= 111.71(1)°, V = 1.5467(7) nm 3, Z = 4, Dx = 1.893g · cm -3, μ(MoKα) = 23.24cm -1, F(000) = 856.00, final R = 0.025 for 1542 unique reflection [I ≥ 3σ(I)]. The bond lengths of Sn-C is 0.148(3) nm, Sn-Cl is 0.23754(9) nm. The title compound exist as a discrete ...