期刊论文

Tang, Si-Ping

英文

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY

2053-2296

2009

65

7

m731

10.1107/S1600536809020753

Construct Program of Key Disciplines in Hunan province; Foundation of Hunan Province Education Office [08 C178]

本校为第一且通讯机构

The title complex, [CuFe(C(5)H(5))(C(20)H(14)N(3))(C(12)H(8)N(2))](ClO(4))(2).C(2)H(3)N, consists of a mononuclear [Cu(C(12)H(8)N(2))(C(25)H(19)FeN(3))](2+) cation, two ClO(4) (-) anions (one of which is disordered over two positions with equal occupancy) and one CH(3)CN solvent mol-ecule. The Cu(II) center has a distorted square-pyramidal coordination with three N atoms of the 4'-ferrocenyl-2,2':6',2''- terpyridine (fctpy) ligand and one 1,10-phenanthroline (phen) N atom in the basal plane and a second phen N atom in the apical position with an axial distance of 2.254 (4) A. The disordered Cl...