The active sites of a mixed Cu/Ce material and the doping effect of typical element (iron, Fe) on the active species and the catalytic behavior of Cu/Ce for CO preferential oxidation in rich H 2 (CO-PROX) were investigated by in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), in situ oxygen storage capacity measurement (OSC) combined with designed temperature-programmed reduction (TPR), along with Raman, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and temperature-programmed desorption/reduction of...