合成了一新型氯桥联铜配位聚合物[(μ-Cl)Cu(BBPY)]＋ n [BBPY：2,6-二(2-苯并咪唑基)吡啶],经 X-射线衍射法测定其结构,属单斜晶系,P2(1)/c 空间群,由氮、氯原子与铜(II)配位,氮对铜(II)配位形成两个五元环,构成中心铜与配位原子的畸变锥形结构,通过氯原子的 Cu(μ-Cl)Cu 桥联作用形成一维链铜配位聚合物。
摘要(英文)：
A new μ-chloro-bridged one-dimensional coordination polymer [(μ-Cl)Cu(BBPY)]+ n (BBPY = 2,6-bis(2-benzimid-azolyl)pyridine)has been synthesized.Its structure was characterized by the X-ray diffraction method.The result of structure analysis indicates that the complex crystallizes in monoclinic with space group P2(1)/c.The copper(II)is coordinated with ni-trogen atom and chlorine atom,forming two stable five-member rings structure,and showing a cone of copper ions adopts a distorted coordination geometry.A one-dimensional chain coordin...
