Solvothermal synthesis, structure and properties of a new 3-D anionic porous framework
作者：
Chen, Man-Sheng;Yang, Ying-Qun;Zhang, Chun-Hua* ;Kuang, Dai-Zhi;Deng, Yi-Fang;...
期刊：
Inorganic Chemistry Communications ,2011年14(2):444-446 ISSN：1387-7003
通讯作者：
Zhang, Chun-Hua
作者机构：
[Deng, Yi-Fang; Chen, Zhi-Min; Kuang, Dai-Zhi; Yang, Ying-Qun; Chen, Man-Sheng; Zhang, Chun-Hua] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
通讯机构：
[Zhang, Chun-Hua] H;Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
关键词：
Gas adsorption;Metal-organic framework;Solvothermal reaction;Zinc(II) complex
摘要：
A new three-dimensional porous Zinc(II) metal-organic framework [NH 2Et2][Zn(BTC)]•H2O (1) was synthesized by the self-assembly of 1,3,5-benzenetricarboxy acid (H3BTC) and Zn(II) salt in diethylformamide (DEF), and characterized by single-crystal X-ray structure determination, thermogravimetric analysis and X-ray powder diffraction studies. The adsorption behavior shows that compound 1 has selective adsorption capacities of CO2 over N2 after the removal of the water molecules within the pores. © 2010 Elsevier B.V. All rights reserved.
语种：
英文
展开
Hydrothermal Synthesis,Crystal Structure and Electrochemical Properties of a Cobalt(Ⅱ)Complex Constructed by 3-(carboxymethoxy)-2-naphthoic Acid
作者：
Li Bi-Hui;Yang Nian-Fa* ;Zhang Chun-Hua;Chen Man-Sheng
期刊：
无机化学学报 ,2011年27(8):1613-1616 ISSN：1001-4861
通讯作者：
Yang Nian-Fa
作者机构：
[Yang Nian-Fa; Li Bi-Hui] Xiangtan Univ, Minist Educ, Coll Chem, Key Lab Environmentally Friendly Chem & Applicat, Xiangtan 411105, Hunan, Peoples R China.;[Chen Man-Sheng; Li Bi-Hui; Zhang Chun-Hua] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
通讯机构：
[Yang Nian-Fa] X;Xiangtan Univ, Minist Educ, Coll Chem, Key Lab Environmentally Friendly Chem & Applicat, Xiangtan 411105, Hunan, Peoples R China.
关键词：
Co(Ⅱ)complex;crystal structure;3-(carboxymethoxy)-2-naphthoic acid;hydrothermal synthesis
摘要：
The title complex,[Co(L)(H_2O)]_n,1,where H_2 L=3-(carboxymethoxy)-2-naphthoic acid,was synthesized through hydrothermal synthesis and its crystal structure was determined by X-ray diffraction analysis.The crystal is monoclinic,space group P2_1 with a=0.505 87(7)nm,b=0.942 88(12)nm,c=1.234 03(16)nm,β=95.015(9),V= 0.586 35(13)nm 3,Z=2,M r =321.14,D c =1.819 g·cm~(-3),μ=1.487 mm~(-1),F(000)=326,R int =0.023 8,R_1 =0.022 8,wR_2 =0.053 2,and the Flack parameter is 0.026(13).In the complex,the cobalt atom is six-coordinated by six oxygen atoms,completing an octahedral geometry.The molecules are connected to form a 2D layer structure bridged by 3-(carboxymethoxy)-2-naphthoic acid.The cyclic voltammetric behavior of the complex was also studied
语种：
英文
展开
由异烟酰胺基间苯二甲酸根构筑的混核钴铕配位聚合物的合成、晶体结构及荧光性质
作者：
Chen Man-Sheng* ;Zeng Ju-Lan;Deng Yi-Fang;Zhang Chun-Hua;Kuang Dai-Zhi;...
期刊：
无机化学学报 ,2011年27(11):2313-2317 ISSN：1001-4861
通讯作者：
Chen Man-Sheng
作者机构：
[Nie Xue; Deng Yi-Fang; Chen Man-Sheng; Kuang Dai-Zhi; Zhang Chun-Hua] Hengyang Normal Univ, Coll Hunan Prov, Dept Chem & Mat Sci, Key Lab Funct Organometall Mat, Hengyang 421008, Hunan, Peoples R China.;[Zeng Ju-Lan] Changsha Univ Sci & Technol, Sch Chem & Biol Engn, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Changsha 410004, Hunan, Peoples R China.
通讯机构：
[Chen Man-Sheng] H;Hengyang Normal Univ, Coll Hunan Prov, Dept Chem & Mat Sci, Key Lab Funct Organometall Mat, Hengyang 421008, Hunan, Peoples R China.
关键词：
3d-4f配合物;晶体结构;氢键;荧光性质
摘要：
由水热法合成了一个混核金属配位聚合物{[CoEu_2(INAIP)_4(H_2O)_6].2.5H_2O}_n(1)(INAIP~(2-)=异烟酰胺基间苯二甲酸根),并对其进行了元素分析、IR及X-射线衍射法表征。晶体结构研究表明:配合物1属于三斜晶系,P1-vector空间群。配合物1是由配体异烟酰胺基间苯二甲酸连接而成的二维双层状结构,该二维层通过氢键拓展为三维超分子结构。配合物1的荧光测试研究表明它具有典型的稀土铕离子红色荧光。
语种：
中文
展开
Structure, Electrochemical and Magnetic Properties of a New Dinuclear Copper(II) Complex: [Cu-2(C12H6O4N2)(2)(2,2 '-bipy)(2)]center dot CH3OH
作者：
Yang, Ying-Qun* ;Chen, Man-Sheng;Li, Wei;Chen, Zhi-Min
期刊：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES ,2011年66(9):894-898 ISSN：0932-0776
通讯作者：
Yang, Ying-Qun
作者机构：
[Chen, Zhi-Min; Yang, Ying-Qun; Li, Wei; Chen, Man-Sheng] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
通讯机构：
[Yang, Ying-Qun] H;Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
关键词：
Copper(II) complex;Crystal structure;Magnetic properties
摘要：
Assembly reaction of copper(I) chloride, 2,2'-bipyridine-3,3'-dicarboxylic acid (H2L) and 2,2'-bipyridine results in the formation of a new complex [Cu2(C12H6O4N2) 2(2,2'-bipy)2] CH3OH (1). In 1, two L 2- ligands link two Cu(II) ions to form a dinuclear structure. The electrochemical and magnetic properties of 1 were investigated. The results show that the electron transfer is irreversible in the electrode reaction, corresponding to Cu(II)/Cu(0). 1 is paramagnetic and exhibits a weak antiferromagnetic coupling. © 2011 Verlag der Zeitschrift für Naturforschung, Tübingen.
语种：
英文
展开
Solvothermal synthesis, structure and properties of a new 3-D Cu(I)–Gd(III) heterometallic coordination framework
作者：
Chen, Man-Sheng* ;Deng, Yi-Fang;Zhang, Chun-Hua;Kuang, Dai-Zhi;Nie, Xue;...
期刊：
Inorganic Chemistry Communications ,2011年14(6):944-947 ISSN：1387-7003
通讯作者：
Chen, Man-Sheng
作者机构：
[Deng, Yi-Fang; Nie, Xue; Kuang, Dai-Zhi; Liu, Yang; Chen, Man-Sheng; Zhang, Chun-Hua] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
通讯机构：
[Chen, Man-Sheng] H;Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
关键词：
Heterometallic complex;Magnetism;Metal-organic framework;Solvothermal reaction
摘要：
A new 3d-4f heterometallic coordination polymer, [CuGd2(INAIP) 3(HCOO)(H2O)3]·3H2O (1), [H2INAIP = 5-(isonicotinamido)isophthalic acid] has been synthesized and characterized by single crystal X-ray diffraction analysis. The results of structural analyses show that 1 has a two-fold interpenetrated 3D coordination framework with a rare sqc27 topology. In addition, thermogravimetric and magnetic properties were also investigated. © 2011 Elsevier B.V.
语种：
英文
展开
Single-crystal-to-single-crystal transformations and selective adsorption of porous copper(II) frameworks
作者：
Chen, Man-Sheng;Chen, Min;Takamizawa, Satoshi;Okamura, Taka-aki;Fan, Jian;...
期刊：
Chemical Communications ,2011年47(13):3787-3789 ISSN：1359-7345
通讯作者：
Sun, Wei-Yin
作者机构：
[Fan, Jian; Sun, Wei-Yin; Chen, Min; Chen, Man-Sheng] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Sch Chem & Chem Engn,Nanjing Natl Lab Microstruct, Nanjing 210093, Peoples R China.;[Chen, Man-Sheng] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.;[Takamizawa, Satoshi] Yokohama City Univ, Grad Sch Nanobiosci, Kanazawa Ku, Kanagawa 2360027, Japan.;[Okamura, Taka-aki] Osaka Univ, Dept Macromol Sci, Grad Sch Sci, Osaka 5600043, Japan.
通讯机构：
[Sun, Wei-Yin] N;Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Sch Chem & Chem Engn,Nanjing Natl Lab Microstruct, Nanjing 210093, Peoples R China.
摘要：
A unique 4-fold interpenetrated (10,3)-b copper(ii) framework exhibits reversible dehydration and rehydration in a single-crystal-to-single-crystal (SC-SC) process, and the dehydrated material can encapsulate CH3OH molecules, again in a SC-SC fashion, and shows selective adsorption of H 2 and CO2 over N2. © The Royal Society of Chemistry.
语种：
英文
展开
Synthesis, Crystal Structure, and Properties of the 3D Porous Framework [Zn(INAIP)]center dot DMA center dot H2O
作者：
Chen, Man-Sheng* ;Tan, Xiong-Wen;Zhang, Chun-Hua;Kuang, Dai-Zhi
期刊：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE ,2011年637(9):1220-1223 ISSN：0044-2313
通讯作者：
Chen, Man-Sheng
作者机构：
[Kuang, Dai-Zhi; Tan, Xiong-Wen; Chen, Man-Sheng; Zhang, Chun-Hua] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
通讯机构：
[Chen, Man-Sheng] H;Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
关键词：
Zinc;Solvothermal reactions;Porous frameworks;Sorption behavior;Metal-organic frameworks
摘要：
A new three-dimensional (3D) porous framework [Zn(INAIP)] ·DMA·H2O (1) [INAIP = 5-(isonicotinamido)isophthalate, DMA = N,N′-dimethylacetamide] was synthesized by solvothermal methods and characterized by single-crystal and powder X-ray diffraction, as well as thermogravimetric analysis. The results of X-ray diffraction analyses revealed that complex 1 has an unusual 3D architecture with the (3,6)-connected rutile (rtl) topology. The adsorption behavior shows that compound 1 exhibits selective adsorptions of CO2 over N2 after the removal of the solvent molecules within the pores. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
语种：
英文
展开
Synthesis, structure and property of lanthanide–organic frameworks with pyridyl- and carboxylate-containing ligand
作者：
Chen, Man-Sheng;Fan, Jian;Okamura, Taka-aki;Lv, Gao-Chao;Sun, Wei-Yin*
期刊：
Inorganica Chimica Acta ,2011年366(1):268-274 ISSN：0020-1693
通讯作者：
Sun, Wei-Yin
作者机构：
[Lv, Gao-Chao; Fan, Jian; Sun, Wei-Yin; Chen, Man-Sheng] Nanjing Univ, Sch Chem & Chem Engn, Nanjing Natl Lab Microstruct, Coordinat Chem Inst,State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China.;[Chen, Man-Sheng] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.;[Okamura, Taka-aki] Osaka Univ, Grad Sch Sci, Dept Macromol Sci, Osaka 5600043, Japan.
通讯机构：
[Sun, Wei-Yin] N;Nanjing Univ, Sch Chem & Chem Engn, Nanjing Natl Lab Microstruct, Coordinat Chem Inst,State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China.
关键词：
Hydrothermal reaction;Lanthanide complex;Luminescent property
摘要：
Three new lanthanide-organic frameworks {[La(IP-py)(HIP-py)(H 2O)2]·H2O}n (1), {[Sm 2(IP-py)2(IP-pyH)2(H2O) 2]·12H2O}n (2) and {[Tb 3(IP-py)4(IP-pyH)(H2O)5] ·9H2O}n (3) have been prepared by reactions of the corresponding lanthanide salt with 5-(isonicotinamido)isophthalic acid (H 2IP-py). The complexes have been fully characterized by means of IR, elemental analyses and single-crystal X-ray diffraction. In compounds 1-3, the lanthanide centers are eight- and nine-coordinated with different coordination geometries and the carboxylate groups of the ligand show different coordination modes leading to the formation of different 2D network structures which are well-defined by the bulky and inert functional groups. Interestingly an unprecedented 2D network of water molecules was observed in complex 2. The luminescent properties of complexes 2 and 3 were investigated. © 2010 Elsevier B.V. All rights reserved.
语种：
英文
展开
Three-dimensional 3d-4f heterometallic coordination polymers: syntheses, structures and properties
作者：
Chen, Man-Sheng;Zhao, Yue;Okamura, Taka-Aki;Su, Zhi;Sun, Wei-Yin* ;...
期刊：
Supramolecular Chemistry ,2011年23(1-2):117-124 ISSN：1061-0278
通讯作者：
Sun, Wei-Yin
作者机构：
[Zhao, Yue; Sun, Wei-Yin; Su, Zhi; Chen, Man-Sheng] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Sch Chem & Chem Engn,Nanjing Natl Lab Microstruct, Nanjing 210093, Peoples R China.;[Chen, Man-Sheng] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.;[Ueyama, Norikazu; Okamura, Taka-Aki] Osaka Univ, Grad Sch Sci, Dept Macromol Sci, Osaka 5600043, Japan.
通讯机构：
[Sun, Wei-Yin] N;Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Sch Chem & Chem Engn,Nanjing Natl Lab Microstruct, Nanjing 210093, Peoples R China.
会议名称：
5th International Symposium on Macrocyclic and Supramolecular Chemistry
会议时间：
JUN 06-10, 2010
会议地点：
Nara, JAPAN
会议主办单位：
[Chen, Man-Sheng;Zhao, Yue;Su, Zhi;Sun, Wei-Yin] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Sch Chem & Chem Engn,Nanjing Natl Lab Microstruct, Nanjing 210093, Peoples R China.^[Chen, Man-Sheng] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.^[Okamura, Taka-Aki;Ueyama, Norikazu] Osaka Univ, Grad Sch Sci, Dept Macromol Sci, Osaka 5600043, Japan.
关键词：
heterometallic coordination polymers;magnetic property;photoluminescence property
摘要：
Six new 3d-4f heterometallic coordination polymers, {[Ln4Cu2(INAIP)8(H2O)15]·14H2O}n [Ln = La (1), Pr (2), Nd (3)] and {[LnCo0.5(INAIP)2(H2O)2]·2H2O}n [Ln = Tb (4), Dy (5), Yb (6), H2INAIP = 5-(isonicotinamido)isophthalic acid] have been synthesised and characterised by single crystal X-ray diffraction analysis. The results of structural analyses showed that 1–3 are isomorphous showing two-fold interpenetrated three-dimensional (3D) coordination framework, while 4–6 have the same non-interpenetrated 3D structure with 2D (4, 4) lanthanide-carboxylate layers. The results revealed that the different transition metal centres have great influence on the structures of the resulted complexes in this system. In addition, thermogravimetric and magnetic properties of 1–6, and photoluminescence of 4 were investigated.
语种：
英文
展开
无机化学实验教学模式的改革与实践
作者：
陈满生;邓奕芳;陈志敏;邹建陵;杨颖群;...
期刊：
衡阳师范学院学报 ,2011年32(06):143-145 ISSN：1673-0313
作者机构：
功能金属有机材料湖南省普通高等学校重点实验室,湖南衡阳421008;衡阳师范学院化学与材料科学系,湖南衡阳421008;衡阳师范学院化学与材料科学系,湖南衡阳,421008;[杨颖群; 陈志敏; 陈满生; 易正戟] 功能金属有机材料湖南省普通高等学校;[邹建陵; 罗炳初; 邓奕芳] 衡阳师范学院
关键词：
无机化学实验;教学模式;实践
摘要：
以培养“厚基础、宽口径、强能力、高素质、重应用”人才为目的，从教学内容、教学方法和考核方式等方面对无机化学实验教学进行改革，建立了“基础型＋设计型＋创新研究型”实验教学新模式。实践证明，这种教学模式能充分调动学生的实验能动性，有利于培养学生良好的科学素质和创新能力。
语种：
中文
展开
Hydrothermal Synthesis,Crystal Structure and Luminescence Property of a 2D Eu(Ⅲ)Complex Based on 5-(Isonicotinamido)isophthalic Acid
作者：
Deng Yi-Fang;Chen Man-Sheng* ;Zhang Chun-Hua;Kuang Dai-Zhi;Chen Zhi-Min
期刊：
无机化学学报 ,2011年27(8):1654-1658 ISSN：1001-4861
通讯作者：
Chen Man-Sheng
作者机构：
[Deng Yi-Fang; Chen Man-Sheng; Kuang Dai-Zhi; Zhang Chun-Hua; Chen Zhi-Min] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
通讯机构：
[Chen Man-Sheng] H;Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
关键词：
Eu(Ⅲ)complex;crystal structure;5-(isonicotinamido)isophthalic acid;hydrothermal synthesis
摘要：
The title complex,{[Eu(L)(HL)]·2H_2O}_n 1,where H_2 L=5-(isonicotinamido)isophthalic acid,was synthes-ized and its crystal structure was determined by X-ray diffraction analysis.The crystal is of monoclinic,space group P2_1 /c with a=1.344 02(18)nm,b=1.377 50(18)nm,c=1.623 07(15)nm,β=115.820(8)°,V=2.704 9(6)nm~3,Z=4,M r =757.45,D c =1.860 g·cm~(-3),μ=2.396 mm~(-1),F(000)=1 504,R int =0.051 4,R_1 =0.032 2,wR 2 =0.089 1.In the complex,the central Eu(Ⅲ)atom is eight-coordinated by eight carboxylate oxygen atoms,completing a distorted bicapped trigonal prismatic geometry.The molecules are connected to form a 2D bilayer structure bridged by 5-(isonicotinamido)isophthalic acid
语种：
英文
展开
Poly[[tetraaquatetrakis-[μ 3-5-(pyridine-4-carboxamido) -isophthalato]cobalt(II)digadolinium(III)] tetra-hydrate]
作者：
Deng, Yi-Fang;Chen, Man-Sheng* ;Zhang, Chun-Hua;Kuang, Dai-Zhi
期刊：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY ,2011年67(10):m1431-m1432 ISSN：2053-2296
通讯作者：
Chen, Man-Sheng
作者机构：
[Deng, Yi-Fang; Kuang, Dai-Zhi; Chen, Man-Sheng; Zhang, Chun-Hua] Hengyang Normal Univ, Dept Chem & Mat Sci, Key Lab Funct Organometall Mat, Hengyang 421008, Hunan, Peoples R China.
通讯机构：
[Chen, Man-Sheng] H;Hengyang Normal Univ, Dept Chem & Mat Sci, Key Lab Funct Organometall Mat, Hengyang 421008, Hunan, Peoples R China.
关键词：
data-to-parameter ratio = 11.8;mean σ(C-C) = 0.007 Å;R factor = 0.031;single-crystal X-ray study;T = 293 K;wR factor = 0.070
摘要：
In the centrosymmetric polymeric title compound, {[CoGd 2(C 14H 8N 2O 5) 4(H 2O) 4]·4H 2O} n, the Gd III cation is coordinated by one water molecule and four pyridine-4-carboxamido-isophthalate (L) anions in a distorted square-anti-prismatic arrangement, while the Co II cation, located on an inversion center, is coordinated by two pyridyl-N atoms, two carboxylate-O atoms and two water molecules in a distorted octa-hedral geometry. The asymmetric unit contains two anionic L ligands: one bridges two Gd cations and one Co cation through two carboxyl groups and one pyridine-N atom; the other bridges two Gd cations and one Co cation through two carboxyl groups and the uncoordinated pyridine-N atom is hydrogen-bonded to the adjacent coordinated water molecule. Extensive O-H⋯O and N-H⋯O hydrogen bonds are present in the crystal structure.
语种：
英文
展开
Poly[[tetraaquatetrakis[μ3-5-(pyridine-4-carboxamido) isophthalato]cobalt(II)-diholmium(III)] tetrahydrate]
作者：
Deng, Yi-Fang;Chen, Man-Sheng* ;Zhang, Chun-Hua;Nie, Xue
期刊：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY ,2011年67(11):m1574-m1575 ISSN：2053-2296
通讯作者：
Chen, Man-Sheng
作者机构：
[Deng, Yi-Fang; Nie, Xue; Chen, Man-Sheng; Zhang, Chun-Hua] Hengyang Normal Univ, Key Lab Funct Organometall Mat, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
通讯机构：
[Chen, Man-Sheng] H;Hengyang Normal Univ, Key Lab Funct Organometall Mat, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
摘要：
In the centrosymmetric polymeric title compound, {[CoHo2(C 14H8N2O5)4(H 2O)4]·4H2O}n, the Ho III ion is coordinated by one water molecule and four 5-(pyridine-4-carboxamido)-isophthalate (L) ligands in a distorted square-antiprismatic arrangement. The CoII ion, located on an inversion center, is coordinated by two pyridine N atoms, two carboxylate O atoms and two water molecules in a distorted octa-hedral geometry. One L ligand bridges two Ho ions and one Co ion through two carboxylate groups and one pyridine N atom. The other L ligand bridges two Ho ions and one Co ion through two carboxylate groups, while the uncoordinated pyridine N atom accepts a hydrogen bond from an adjacent coordinated water molecule. Extensive O - H⋯O, N - H⋯O and O - H⋯N hydrogen bonding is present in the crystal. © Deng et al. 2011.
语种：
英文
展开
Porous zinc(II) frameworks with 5-(isonicotinamido)isophthalate: Syntheses, structures and properties
作者：
Chen, Man-Sheng;Chen, Min;Okamura, Taka-aki;Sun, Wei-Yin* ;Ueyama, Norikazu
期刊：
Microporous and Mesoporous Materials ,2011年139(1-3):25-30 ISSN：1387-1811
通讯作者：
Sun, Wei-Yin
作者机构：
[Sun, Wei-Yin; Chen, Min; Chen, Man-Sheng] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Sch Chem & Chem Engn,Nanjing Natl Lab Microstruct, Nanjing 210093, Peoples R China.;[Chen, Man-Sheng] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.;[Ueyama, Norikazu; Okamura, Taka-aki] Osaka Univ, Dept Macromol Sci, Grad Sch Sci, Osaka 5600043, Japan.
通讯机构：
[Sun, Wei-Yin] N;Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Sch Chem & Chem Engn,Nanjing Natl Lab Microstruct, Nanjing 210093, Peoples R China.
关键词：
Coordination polymer;Zinc(II) complex;Crystal structure;Sorption property
摘要：
Two new three-dimensional (3D) coordination polymers [Zn(INAIP)] ·2DMF (1) and [Zn(INAIP)]·9H<inf>2</inf>O (2) have been synthesized by reactions of Zn(NO<inf>3</inf>)<inf>2</inf>·6H <inf>2</inf>O with 5-(isonicotinamido)isophthalic acid (H<inf>2</inf>INAIP) in N,N-dimethylformamide (DMF) and N,N-diethylformamide (DEF), respectively. The change of solvent leads to the formation of neutral frameworks with different structure, topology as well as different pore size and shape. The X-ray crystallographic structural analysis revealed that complex 1 is an unusual 3D architecture with (3, 6)-connected rutile (rtl) topology containing two-dimensional (2D) (4, 4) networks, while the 3D framework in 2 has (3, 6)-connected (4<sup>2</sup>·6)<inf>2</inf>(4<sup>4</sup>·6 <sup>2</sup>·8<sup>6</sup>·10<sup>3</sup>) topology with 2D kagome´layers. In addition, the stabilities, luminescence and adsorption properties of the complexes were investigated. ©2010 Elsevier Inc. All rights reserved.
语种：
英文
展开
Crystal structure of aqua(1H-imidazol)-(μ3-5- isonicotmamidoisophthalato-κ2 O1, O 3-κ1N1)iron(II) monohydrate, Fe(H 2O)(C3H4N2)(C14H 8N2O5) · H2O
作者：
Chen, Man-Sheng;Deng, Yi-Fang;Kuang, Dai-Zhi;Zhang, Chun-Hua
期刊：
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES ,2011年226(1):25-26 ISSN：1433-7266
通讯作者：
Chen, M.-S.
作者机构：
Key Laboratory of Functional Organometallic Materials, Hengyang Normal University, Department of Chemistry and Materials Science, Hengyang 421008, Hunan, China
通讯机构：
Key Laboratory of Functional Organometallic Materials, Hengyang Normal University, Department of Chemistry and Materials Science, China
摘要：
C17H16FeN4O7, monoclinic, P121/c1 (no. 14), a = 7.696(5) Å, b = 17.96(1) Å, c = 12.778(9) Å, β = 102.001(2)°, V = 1727.7 Å3, Z = 4, Rgt(F) = 0.045, wRref(F2) = 0.118, T = 296K. © by Oldenbourg Wissenschaftsverlag, München.
语种：
英文
展开
Crystal structure of diaqua(4,4 '-bipyridine-N,N ')-bis(2-benzoylbenzoato)-cadmium(II) dihydrate, Cd(C14H9O3)(2)(C10H8N2)(H2O)(2) center dot 2H(2)O
作者：
Chen, Zhi-Min* ;Yang, Ying-Qun;Zou, Jian-Ling;Kuang, Dai-Zhi;Zhang, Fu-Xing;...
期刊：
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES ,2011年226(3):337-338 ISSN：1433-7266
通讯作者：
Chen, Zhi-Min
作者机构：
[Chen, Zhi-Min; Zhang, Fu-Xing; Kuang, Dai-Zhi; Yang, Ying-Qun; Wang, Jian-Qiu; Zou, Jian-Ling; Chen, Man-Sheng] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
通讯机构：
[Chen, Zhi-Min] H;Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
摘要：
C38H34CdN2O10, monoclinic, P12/c1 (no. 13), a = 12.923(3) Å, b = 11.651 (2) Å, c = 13.133(3) Å, β=115.88(3)°, V= 1779.1 Å3, Z= 2, R gt(F)=0.032, wRref(F2) = 0.079, T= 293 K. © by Oldenbourg Wissenschaftsverlag, München.
语种：
英文
展开
Metal-organic frameworks with pyridyl- and carboxylate-containing ligands: Syntheses, structures and properties
作者：
Chen, Man-Sheng;Bai, Zheng-Shuai;Okamura, Taka-aki;Su, Zhi;Chen, Shui-Sheng;...
期刊：
CrystEngComm ,2010年12(6):1935-1944 ISSN：1466-8033
通讯作者：
Sun, Wei-Yin
作者机构：
[Bai, Zheng-Shuai; Sun, Wei-Yin; Chen, Shui-Sheng; Su, Zhi; Chen, Man-Sheng] Nanjing Univ, Sch Chem & Chem Engn, Inst Coordinat Chem, State Key Lab Coordinat Chem,Nanjing Natl Lab Mic, Nanjing 210093, Peoples R China.;[Chen, Man-Sheng] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.;[Ueyama, Norikazu; Okamura, Taka-aki] Osaka Univ, Grad Sch Sci, Dept Macromol Sci, Osaka 5600043, Japan.
通讯机构：
[Sun, Wei-Yin] N;Nanjing Univ, Sch Chem & Chem Engn, Inst Coordinat Chem, State Key Lab Coordinat Chem,Nanjing Natl Lab Mic, Nanjing 210093, Peoples R China.
摘要：
Assembly reactions of pyridyl- and carboxylate-containing ligand 5-(isonicotinamido)isophthalic acid (H2INAIP) with corresponding metal salts result in formation of six new coordination polymers, namely {[Mn(INAIP)(DMF)]·0.5DMF}n (1), {[Mn(INAIP)(H 2O)2]·4H2O}n (2), {[Co(INAIP)(H2O)]·2H2O}n (3), {[Co(INAIP)(bpy)0.5]}n (4), {[Co(INAIP)(Him)(H 2O)]·H2O}n (5), and {[Cu(INAIP)(Him) (H2O)]·H2O}n (6) (DMF = N,N-dimethylformamide, bpy = 4,4′-bipyridine, Him = imidazole). The results of single-crystal X-ray diffraction analysis indicate that 1 is a two-fold interpenetrated three-dimensional (3D) framework with sra topology, complexes 2, 5 and 6 have two-dimensional (2D) network structure with (6,3) topology, while 3 and 4 have infinite 2D bi-layer structure with different topologies. Complex 3 exhibits a 4-connected network with the Schläfli symbol (43·63), and 4 displays a (4,5)-connected net with Schläfli symbol (43·52·6) (43·55·62). The magnetic and adsorption properties of the complexes were investigated. © The Royal Society of Chemistry 2010.
语种：
英文
展开
Hydrothermal Syntheses,Crystal Structures and Magnetic Property of Two Copper(Ⅱ) Complexes Constructed from 5-(Isonicotinamido) isophthalic Acid and N-donor Ligands
作者：
Chen Man-Sheng;Luo Li;Chen Shui-Sheng;Su Zhi;Sun Wei-Yin*
期刊：
无机化学学报 ,2010年26(12):2227-2232 ISSN：1001-4861
通讯作者：
Sun Wei-Yin
作者机构：
[Sun Wei-Yin; Luo Li; Chen Shui-Sheng; Chen Man-Sheng; Su Zhi] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Coordinat Chem Inst, Nanjing 210093, Peoples R China.;[Chen Man-Sheng] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
通讯机构：
[Sun Wei-Yin] N;Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Coordinat Chem Inst, Nanjing 210093, Peoples R China.
关键词：
5-(isonicotinamido)isophthalic acid;crystal structure;hydrothermal synthesis;magnetic property
摘要：
Two Cu(II) complexes [Cu(INAIP)(bbi)]·5H2O (1) and [Cu(INAIP)(phen)(H2O)]·H2O (2) were obtained by hydrothermal reactions of CuCl2·2H2O with 5-(isonicotinamido) isophthalic acid (H2INAIP) and N-donor ligands of 1,1′-(1,4-butanediyl)-bis(imidazole) (bbi) and 1,10-phenanthroline (phen), respectively. Both compounds crystallize in monoclinic space group C2/c. Single crystal X-ray diffraction analysis revealed that the bbi ligands connect [Cu(INAIP)] ID chains to form 2D bi-layers in complex 1, while complex 2 displays a ID chain structure, extending to 2D net through the π-π interactions. Complexes 1 and 2 are finally extended to 3D supramolecular structures by hydrogen bonding interactions. In addition, the magnetic property of complexes 1 and 2 has been investigated in the temperature range of 1.8~300 K, and the results show the weak antiferromagnetic interactions between the two Cu(II) ions bridged by carboxylate groups in 1, and the paramagnetic behavior of 2. CCDC: 781788,1; 781789, 2.
语种：
英文
展开
Syntheses and characterization of inorganic–organic hybrids with 4-(isonicotinamido)phthalate and some divalent metal centers
作者：
Chen, Man-Sheng;Hu, Qin;Bai, Zheng-Shuai;Okamura, Taka-aki;Su, Zhi;...
期刊：
Polyhedron ,2010年29(12):2454-2461 ISSN：0277-5387
通讯作者：
Sun, Wei-Yin
作者机构：
[Bai, Zheng-Shuai; Hu, Qin; Sun, Wei-Yin; Su, Zhi; Chen, Man-Sheng] Nanjing Univ, Nanjing Natl Lab Microstruct, Sch Chem & Chem Engn, Coordinat Chem Inst,State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China.;[Chen, Man-Sheng] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.;[Ueyama, Norikazu; Okamura, Taka-aki] Osaka Univ, Grad Sch Sci, Dept Macromol Sci, Toyonaka, Osaka 5600043, Japan.
通讯机构：
[Sun, Wei-Yin] N;Nanjing Univ, Nanjing Natl Lab Microstruct, Sch Chem & Chem Engn, Coordinat Chem Inst,State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China.
关键词：
Inorganic-organic hybrid framework;Magnetic property;Nonlinear optical property;Photoluminescence property;Topology
摘要：
Four new inorganic-organic hybrid frameworks [Mn(L)(H2O)(2)](n) (1), {[Co(L)(H2O)(3)]center dot 2H(2)O-CH3OH}(n) (2), {[Zn(L)(H2O)]center dot H2O) (3) and [Cd(HL)(2)](n) (4) [H2L = 4-(isonicotinamido)phthalic acid] have been synthesized and characterized by single-crystal X-ray diffraction analysis. Complex 1 has three-dimensional (3D) structure and topology related to SrAl2 (sra) with Schlafli symbol of (4(.)(2)6(3).8). And 2 displays (3,3)-connected two-dimensional (2D) network with (4.8(2)) topology, while 3 exhibits a uninodal (3,3)-connected (6,3) 2D network, which is further linked by N-H center dot center dot center dot O hydrogen bonding interactions to give 3D structure with hms topology and Schlafli symbol of (6(3))(6(9).8). Complex 4 with partial deprotonated HL- ligands also has a 2D network structure. In addition, the magnetic property of 1, nonlinear optical property of 3 and photoluminescence of 3 and 4 were investigated. (C) 2010 Elsevier Ltd. All rights reserved.
语种：
英文
展开
Crystal structure of diaqua-bis(3,5-bis(isonicotinamido)benzoato)cobalt(II) tetrahydrate, Co(H2O)(2)(C19H13N4O4)(2) center dot 4H(2)O
作者：
Deng, Yi-Fang;Tan, Xiong-Wen;Kuang, Dai-Zhi* ;Chen, Man-Sheng
期刊：
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES ,2010年225(2):301-302 ISSN：1433-7266
通讯作者：
Kuang, Dai-Zhi
作者机构：
[Deng, Yi-Fang; Kuang, Dai-Zhi; Tan, Xiong-Wen; Chen, Man-Sheng] Hengyang Normal Univ, Key Lab Funct Organometall Mat, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
通讯机构：
[Kuang, Dai-Zhi] H;Hengyang Normal Univ, Key Lab Funct Organometall Mat, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
摘要：
C38H38CoN8O14, monoclinic, C12/c1 (no. 15), a = 17.871(2) Å, b = 10.632(1) Å, c = 21.773(2) Å, β = 106.031(1)°, V = 3976.3 Å3, Z = 4, Rgt(F) = 0.071, wRref(F2) = 0.183, T = 293 K. © by Oldenbourg Wissenschaftsverlag, M̈unchen.
语种：
英文
展开
