期刊：
Chinese Journal of Structural Chemistry,2014年33(12):1849-1853 ISSN：0254-5861
通讯作者：
Yang Ying-Qun
作者机构：
[Zeng Rong-Ying; Yang Ying-Qun; Tang Si-Ping] Hengyang Normal Univ, Dept Chem & Mat Sci, Key Lab Funct Organometall Mat Hunan Prov Coll, Hengyang 421008, Peoples R China.
通讯机构：
[Yang Ying-Qun] H;Hengyang Normal Univ, Dept Chem & Mat Sci, Key Lab Funct Organometall Mat Hunan Prov Coll, Hengyang 421008, Peoples R China.
关键词：
cadmium(II) complex;2-benzoylbenzoic acid;fluorescent and magnetic properties
摘要：
A new cadmium(II) complex Cd(OBBA)2(2,2A-bipy)2 with 2-benzoylbenzoic acid(HOBBA) and 2,2-bipyridine(2,2A-bipy) as ligands has been synthesized. Crystal data for the complex are as follows: monoclinic, space group P21/c with a = 16.402(3), b = 10.4191(18), c = 23.395(4) A, β = 91.765(2)o, V = 3996.2(12) A3, Dc = 1.455 gAcm-3, Z = 4, μ(Mo Kα) = 0.603 mm-1, F(000) = 1784, the final R = 0.0218 and w R = 0.0558. In the electrode reaction, its electron transfer is quasi reversible and the electrode reaction corresponds to Cd(II)/Cd(0). Under 618 nm radiation, the title complex shows a strong fluorescent band at around 326 nm. In addition, in the range of 2~300 K, this complex displays diamagnetic property.
作者机构：
[张复兴; 唐文清; 冯泳兰] Department of Chemistry and Materials Science, Key Laboratory of Functional Organometallic Materials, Hengyang Normal University, Hengyang, Hunan 421008, China;College of Resources and Environment, Hunan Agricultural University, Changsha, Hunan 410128, China;[Zeng R.-Y.] Department of Chemistry and Materials Science, Key Laboratory of Functional Organometallic Materials, Hengyang Normal University, Hengyang, Hunan 421008, China, College of Resources and Environment, Hunan Agricultural University, Changsha, Hunan 410128, China
通讯机构：
[Zeng, R.-Y.] D;Department of Chemistry and Materials Science, Key Laboratory of Functional Organometallic Materials, Hengyang Normal University, China
作者机构：
[唐文清; 张复兴] Department of Chemistry and Material Science, Hengyang Normal University, Key Laboratory of Functional Organometallic Materials, Hengyang, Hunan 421008, China;[龚道新] College of Resources and Environment, Hunan Agricultural University, Changsha, Hunan 410128, China;[Zeng R.-Y.] Department of Chemistry and Material Science, Hengyang Normal University, Key Laboratory of Functional Organometallic Materials, Hengyang, Hunan 421008, China, College of Resources and Environment, Hunan Agricultural University, Changsha, Hunan 410128, China
通讯机构：
[Tang, W.-Q.] D;Department of Chemistry and Material Science, Hengyang Normal University, Key Laboratory of Functional Organometallic Materials, China
