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The synthesis of multiblock copolymer brush based on DSPAAC and CuAAC click reaction

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成果类型:
期刊论文
作者:
Xiao, Lifen*;Li, Jie;Li, Wenyi;Li, Wei;Huang, Geng
通讯作者:
Xiao, Lifen
作者机构:
[Xiao, Lifen; Huang, Geng; Li, Jie; Li, Wei; Li, Wenyi] Hengyang Normal Univ, Key Lab Funct Organometall Mat Hunan Prov Univ, Coll Chem & Mat Sci, Hengyang 421008, Peoples R China.
通讯机构:
[Xiao, Lifen] H
Hengyang Normal Univ, Key Lab Funct Organometall Mat Hunan Prov Univ, Coll Chem & Mat Sci, Hengyang 421008, Peoples R China.
语种:
英文
期刊:
Journal of Polymer Science
ISSN:
2642-4150
年:
2021
卷:
59
期:
1
页码:
100-107
基金类别:
Hengyang Normal University, Grant/Award Number: 18D06; Scientific Research Foundation of Hunan Provincial Education Department, Grant/Award Numbers: 19A068, 20C0293
机构署名:
本校为第一且通讯机构
院系归属:
化学与材料科学学院
摘要:
Multiblock copolymer brushes have broad application in thermoplastic elastomers, drug delivery, porous materials, and nanolithography due to their unique structure and properties. In this research, a novel multiblock copolymer brush (PHEA-g-PEG)(x)-co- (PEG(23))(y) was synthesized by combining the efficient double strain-promoted azide-alkyne cycloaddition (DSPAAC) and copper-catalyzed azide-alkyne cycloaddition (CuAAC) click reactions. The gel permeation chromatography (GPC), proton nuclear magnetic resonance spectrometer (H-1 NMR), Fourier transform infrared spectroscopy (FT-IR), and atomic ...

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