Copper-Mediated Three-Component Synthesis of Diverse Perfluoroalkylated Fullerenes

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成果类型：

期刊论文

作者：

Liang, Si-Si;Zhou, Qian;Wu, Pei-Xi;Huang, Xiao-Man;Shu, Meng-Ping;...

通讯作者：

Xu, L;Wang, GW

作者机构：

[Huang, Xiao-Man; Xu, Liang; Liang, Si-Si; Zhou, Qian; Wu, Pei-Xi; Shu, Meng-Ping; Xu, L; Zhu, Xiao-Ming] Hengyang Normal Univ, Coll Chem & Mat Sci, Key Lab Funct Organometall Mat Hunan Prov Coll, Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Hunan, Peoples R China.

[Wang, Guan-Wu] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China.

[Wang, Guan-Wu] Anhui Normal Univ, Key Lab Funct Mol Solids, Anhui Lab Mol Based Mat, Minist Educ, Wuhu 241002, Anhui, Peoples R China.

[Wang, Guan-Wu] Anhui Normal Univ, Sch Chem & Mat Sci, Wuhu 241002, Anhui, Peoples R China.

通讯机构：

[Wang, GW ] U

[Xu, L ] H

Hengyang Normal Univ, Coll Chem & Mat Sci, Key Lab Funct Organometall Mat Hunan Prov Coll, Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Hunan, Peoples R China.

Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China.

Anhui Normal Univ, Key Lab Funct Mol Solids, Anhui Lab Mol Based Mat, Minist Educ, Wuhu 241002, Anhui, Peoples R China.

语种：

英文

期刊：

JOURNAL OF ORGANIC CHEMISTRY

ISSN：

0022-3263

年：

2025

卷：

期：

页码：

2022-2035

DOI：

10.1021/acs.joc.4c02753

基金类别：

National Natural Science Foundation of China [21602210]; National Natural Science Foundation of China

机构署名：

本校为第一且通讯机构

院系归属：

化学与材料科学学院

摘要：

The synthesis of perfluoroalkylated fullerenes (PFAFs) holds significant importance due to their enhanced molecular stability, increased lipophilicity, and high electron affinity. Herein, we report a copper-catalyzed multicomponent reaction conducted under aerobic conditions, which enables the production of highly soluble PFAFs with half-wave reduction potentials similar to those of C 60 . Furthermore, the challenges posed by C–F coupling in carbon signal assignment were addressed through fluorine-decoupled carbon spectroscopy, facilitating pr...

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Copper-Mediated Three-Component Synthesis of Diverse Perfluoroalkylated Fullerenes

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