In this paper, the simultaneous voltammetric determination of ascorbic acid (AA) and rutin (Ru) has been achieved at an acetylene black paste electrode modified with multi-walled carbon nanotubes-chitosan composite film (denoted as MWCNTs-CHIT/ABPE). Compared with bare electrode, the peak currents of AA and Ru at MWCNTs-CHIT/ABPE increased greatly and the anodic peak potential difference (Delta E-pa) between AA and Ru are up to 342 mV, which is undoubtedly attributed to the unique characteristics of AB and MWCNTs such as excellent electric conductivity, high surface area and strong adsorptive ...