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Molecular structure regulation and herbicidal activity of dibutyltin aryloxyacetate complexes

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成果类型:
期刊论文
作者:
Yuxing Tan;Huifen Huang;Chengwei Zhang;Sitian Yuan;Wujiu Jiang
通讯作者:
Sitian Yuan<&wdkj&>Wujiu Jiang
作者机构:
[Yuxing Tan; Huifen Huang; Chengwei Zhang; Wujiu Jiang] Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, Key Laboratory of Organometallic New Materials, College of Hunan Province, School of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008, PR China
[Sitian Yuan] Institute of Bast Fiber Crops, Chinese Academy of Agricultural Sciences, Changsha, Hunan 410205, PR China
通讯机构:
[Sitian Yuan] I
[Wujiu Jiang] K
Institute of Bast Fiber Crops, Chinese Academy of Agricultural Sciences, Changsha, Hunan 410205, PR China<&wdkj&>Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, Key Laboratory of Organometallic New Materials, College of Hunan Province, School of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008, PR China
语种:
英文
期刊:
Journal of Molecular Structure
ISSN:
0022-2860
年:
2025
卷:
1320
页码:
139476
基金类别:
CRediT authorship contribution statement Yuxing Tan: Writing – review & editing, Writing – original draft, Methodology, Investigation, acquisition, Formal analysis, Data curation. Huifen Huang: Methodology, Investigation, Formal analysis. Chengwei Zhang: Software, Methodology, Investigation. Sitian Yuan: Resources, Methodology, Investigation, acquisition. Wujiu Jiang: Writing – review & editing, Writing – original draft, Supervision, Project administration, acquisition.
机构署名:
本校为第一且通讯机构
摘要:
Six dibutyltin aryloxyacetate complexes [(X-C6H4OCH2COO)(SnBu2)2(μ3O)(OMe)]2 (A1, B1), [(X-C6H4OCH2COO)2(SnBu2)2(μ3O)]2 (A2, B2), and [(X-C6H4OCH2COO)2SnBu2] (A3, B3) were synthesized and characterized by IR, NMR, HRMS, and TGA techniques. The molecular structure of complexes A1, A3 and B1-B3 was confirmed by single-crystal X-ray crystallography. Complexes A1, B1, A2, and B2 are dimeric carboxylate tetraorganodistannoxanes, displaying a "ladder-like" molecular arrangement. The aryloxyacetate ligands in A1 and B1 adopt a monodentate mode, whil...

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