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Acetylene black paste electrode modified with a molecularly imprinted chitosan film for the detection of bisphenol A

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成果类型:
期刊论文
作者:
Deng, Peihong*;Xu, Zhifeng;Li, Junhua;Kuang, Yunfei
通讯作者:
Deng, Peihong
作者机构:
[Deng, Peihong; Xu, Zhifeng; Li, Junhua; Kuang, Yunfei] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
通讯机构:
[Deng, Peihong] H
Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
语种:
英文
关键词:
Molecular imprinting;Bisphenol A;Chitosan;Acetylene black;Voltammetric sensor
期刊:
Microchimica Acta
ISSN:
0026-3672
年:
2013
卷:
180
期:
9-10
页码:
861-869
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21105024]; Education Department of Hunan Province [11CY002, 12C0536]; Hunan Provincial Natural Science Foundation of ChinaNatural Science Foundation of Hunan Province [11JJ9005]; Key Laboratory of Functional Organometallic Materials of Ordinary University in Hunan Province [12 K125]; Key Discipline Project of Hunan Province; Research Award Fund for Outstanding Young Teachers of Hunan Province
机构署名:
本校为第一且通讯机构
院系归属:
化学与材料科学学院
摘要:
We report on a voltammetric sensor for bisphenol A (BPA) that is based on an acetylene-black paste electrode modified with a chitosan film molecularly imprinted for BPA. The sensor responds linearly to BPA in the 80 nM to 10 μM concentration range, and the detection limit is 60 nM (at an S/N of 3). The use of a molecular imprint provides an efficient way for eliminating interferences from potentially interfering substances. The high sensitivity, selectivity and stability of the sensor demonstrate its practical application for the determination of BPA in plastic sample...

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