期刊论文

中文

计算机与应用化学

1001-4160

2014

31

8

1003-1006

10.11719/com.app.chem20140823

湖南省科技计划项目（2014FJ3060,2014NK086） 湖南省普通高校重点实验室开放基金（13K03,13K04,13K05）及湖南省教育厅科研项目（14C0171）资助

本校为第一机构

醋酸锰与2,2'-联吡啶-3,3'-二甲酸(2,2'-Bipyridine-3,3'-dicarboxylic acid)反应合成一维链状聚合物[Mn(μ_2-η~2-bp3dc)(H_2O)_2]_n,(bp3dc = 2,20-bipyridine-3,30-dicarboxylate),经元素分析、IR和X-射线衍射表征分子结构,该化合物晶体学参数:单斜晶系,空间群C2/c,晶体学数据:a = 1.1648(2) nm,b = 0.80422(15) nm,c = 1.2949(3) nm,β = 100.117(10)°,V = 1.1941 (4) nm~3,Z=4,Dc=1.853 g/cm~3,μ(MoKα) = 1.138 cm~(-1),F(000)=676,R_1 = 0.0317, wR_2 = 0.0733 [对I > 2σ(I)的衍射]和R_1 = 0.0246 , wR_2=0.0703 (对所有的衍射)。共收集3893个数据,其中独立衍射点1390个,可观察衍射[...

A Manganese (II) coordination polymer [Mn(μ2-η2-bp3dc)(H2O)2]n (bp3dc = 2,20-bipyridine-3, 30-dicarboxylate) has been synthesized and characterized by elemental analyses, IR and X-ray diffraction. Crystal data for this complex:monoclinic system, space group C2/c , with a=1.1648(2) nm,b=0.80422(15) nm,c=1.2949(3) nm,β=100.117(10)°,V=1.1941 (4) nm3,Z=4,Dc=1.853 g/cm3,μ(MoKα)=1.138 cm-1, F(000)=676,R1=0.0317, wR2=0.0733 [I>2σ(I) observed reflections] and R1=0.0246 , wR2=0.0703 (all reflections). A total of 3893 reflections collected, 1390 w...