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Capping-ligand free grinding synthesis of luminescent lead halide perovskite nanocrystals

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成果类型:
期刊论文
作者:
Zhang, Ting;Jiang, Chunli;Luo, Rong;Qi, Ruijuan;Liu, Mengqin;...
通讯作者:
Luo, C.
作者机构:
[Jiang, Chunli; Lin, Hechun; Zhang, Ting; Qi, Ruijuan; Luo, Rong; Luo, Chunhua; Peng, Hui] East China Normal Univ, Dept Elect, Key Lab Polar Mat & Devices MOE, Shanghai 200241, Peoples R China.
[Qi, Ruijuan; Peng, Hui] Shanxi Univ, Collaborat Innovat Ctr Extreme Opt, Taiyuan 030006, Shanxi, Peoples R China.
[Liu, Mengqin] Hengyang Normal Univ, Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Peoples R China.
通讯机构:
Key Laboratory of Polar Materials and Devices (MOE), Department of Electronics, East China Normal University, Shanghai, China
语种:
英文
关键词:
Chelation;Chlorine compounds;Grinding (machining);Lead compounds;Luminescence;Methanol;Perovskite;Capping ligands;Chloride ions;Grinding methods;Grinding process;Halide perovskites;Photoluminescence quantum yields;Single-step;Nanocrystals
期刊:
Materials Today Communications
ISSN:
2352-4928
年:
2020
卷:
26
页码:
101926
基金类别:
This work was supported by Natural Science Foundation of Shanghai (No.18ZR1410900) and Shanghai Science and Technology Innovation Action Plan (No. 19JC141670). The authors thank ECNU Multifunctional Platform for Innovation (004 and 006) for technology support. This work was supported by Natural Science Foundation of Shanghai (No. 18ZR1410900 ) and Shanghai Science and Technology Innovation Action Plan (No. 19JC141670 ). The authors thank ECNU Multifunctional Platform for Innovation (004 and 006) for technology support.
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摘要:
Luminescent (trimethylbromomethyl) ammonium lead tribromide ((TMBM)PbBr3) nanocrystals are synthesized by a green single-step mechano-grinding method in large scale. The photoluminescence quantum yield (PL QY) of the obtained (TMBM)PbBr3 nanocrystals is 2.61 %. The luminescence of the nanocrystals can be significantly enhanced by introducing water or methanol during the grinding process. The maximum PL QYs of 7.65 % and 4.69 % are obtained for the nanocrystals prepared by the addition of water and methanol, respectively. The emission light of (TMBM)PbBr3 nanocry...

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