期刊论文

Jiang, Wujiu

英文

Inorganica Chimica Acta

0020-1693

2019

496

119044

10.1016/j.ica.2019.119044

This work was supported by the Hunan Provincial College Student Researchful Study and Innovative Experiment Project (grant number cx1813), Hunan Provincial Natural Science Foundation of China (grant number 2017JJ3003), Hengyang Normal University Discipline Group Construction Project (grant number 18XKQ01) and the Foundation of Key Laboratory of Functional Organometallic Materials, University of Hunan Province (grant number GN19K07).

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Three new diphenyltin complexes, {[p-t-Bu-C6H4(O)C[dbnd]N–N[dbnd]C(Me)COO]Ph2Sn(MeOH)}2 (C1), {[p-MeO-C6H4(O)C[dbnd]N–N[dbnd]C(Me)COO]Ph2Sn(MeOH)}2 (C2) and {[C4H3O(O)C[dbnd]N–N[dbnd]C(Me)COO]Ph2Sn}n (C3), were synthesized by the reactions of diphenyltin dichloride with the corresponding hydrazones. All the complexes were characterized by IR; 1H, 13C, and 119Sn NMR spectroscopy; HRMS; elemental analysis; single-crystal X-ray diffraction and TGA. To test their in vitro antitumour activities, the complexes were evaluated by an MTT assay, and t...