Star-shaped Trinuclear Organometallic Complexes with a Benzo[1,2-b:3,4-b\':5,6-b\'\']trithiophene Triethynyl Backbone: Syntheses, (Spectro-)Electrochemistry, and Theoretical Calculations - 成果

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Star-shaped Trinuclear Organometallic Complexes with a Benzo[1,2-b:3,4-b':5,6-b'']trithiophene Triethynyl Backbone: Syntheses, (Spectro-)Electrochemistry, and Theoretical Calculations

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作者信息关键词期刊信息基础信息归属信息摘要

成果类型：

期刊论文

作者：

Gao, Chengshuo;Xu, Meng;Liu, Zhengji;Ou, Juntong;Feng, Weijie;...

通讯作者：

Zhang, Qian;Ou, YP;Liu, SH

作者机构：

[Ou, Ya-Ping; Ou, YP; Feng, Weijie; Gao, Chengshuo; Zhang, Qian; Ou, Juntong; Liu, Zhengji; Li, Yule] Hengyang Normal Univ, Key Lab Funct Organometall Mat Hunan Prov Coll, Coll Chem & Mat Sci, Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Hunan, Peoples R China.

[Liu, Sheng Hua; Liu, SH; Xu, Meng] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.

通讯机构：

[Ou, YP ; Zhang, Q] H

[Liu, SH ] C

Hengyang Normal Univ, Key Lab Funct Organometall Mat Hunan Prov Coll, Coll Chem & Mat Sci, Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Hunan, Peoples R China.

Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.

语种：

英文

关键词：

Trimetal ethynyl complexes;Electrochemistry;Spectroelectrochemistry;Electronic communication;Bridge-localized oxidation

期刊：

Journal of Organometallic Chemistry

ISSN：

0022-328X

年：

2025

卷：

1034

页码：

123668

DOI：

10.1016/j.jorganchem.2025.123668

基金类别：

National Natural Science Foundation of China [21602049]; Natural Science Foundation of Hunan Province, China [2021JJ30058, 2017JJ3004]; Scientific Research Projects of Education Department of Hunan Province [21A0441]; National Training Program of Innovation and Entrepreneurship for Undergraduates [202312659001]; Aid Programs for Technology Innovative Team; Key Discipline in Education Department of Hunan Province; Functional Metal-Organic Compounds of Hunan Science and Technology Innovation Team; Support Plan for Talents in Hengyang Normal University

机构署名：

本校为第一且通讯机构

院系归属：

化学与材料科学学院

摘要：

The two star-shaped trimetal ethynyl complexes benzo[1,2-b:3,4-b':5,6-b'']trithiophene (BTT)][MCp*(dppe) 2 ] 3 ( 3 , M = Ru; 4 , M = Fe) are synthesized and characterized by NMR spectroscopy, elemental analysis and X-ray single crystal diffraction. The influence of different metals linked with identical bridge core on the electronic properties of 3 and 4 under various redox states are studied using electrochemical (cyclic and square wave voltammetry) and spectroelectrochemical (in situ UV-Vis-NIR and IR spectroscopy) methods and DFT calcula...

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Star-shaped Trinuclear Organometallic Complexes with a Benzo[1,2-b:3,4-b':5,6-b'']trithiophene Triethynyl Backbone: Syntheses, (Spectro-)Electrochemistry, and Theoretical Calculations

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