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Combination of hydrophobic effect and electrostatic interaction in imprinting for achieving efficient recognition in aqueous media

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成果类型:
期刊论文
作者:
Xu, Zhifeng*;Kuang, Daizhi;Feng, Yonglan;Zhang, Fuxing
通讯作者:
Xu, Zhifeng
作者机构:
[Xu, Zhifeng; Zhang, Fuxing; Feng, Yonglan; Kuang, Daizhi] Hengyang Normal Univ, Dept Chem & Mat Sci, Coll Hunan Prov, Key Lab Funct Organomet Mat, Hengyang 421008, Peoples R China.
通讯机构:
[Xu, Zhifeng] H
Hengyang Normal Univ, Dept Chem & Mat Sci, Coll Hunan Prov, Key Lab Funct Organomet Mat, Hengyang 421008, Peoples R China.
语种:
英文
关键词:
Molecular imprinting;Acifluorfen;beta-Cyclodextrin;Molecular recognition
期刊:
Carbohydrate Polymers
ISSN:
0144-8617
年:
2010
卷:
79
期:
3
页码:
642-647
基金类别:
This study was supported by the Open Fund Project of Key Laboratory in Hunan Universities and Scientific Research Program of Hengyang Science and Technology Bureau (No. 2008KS035 ).
机构署名:
本校为第一且通讯机构
院系归属:
化学与材料科学学院
摘要:
An acifluorfen-imprinted polymer (P1) was prepared by the combined use of bismethacryloyl-β-cyclodextrin (BMA-β-CD) and 4-vinylpyridine (4-VP) as functional monomers. Compared with the molecularly imprinted polymers (MIPs) using only BMA-β-CD or 4-VP as a functional monomer, P2 and P3, respectively, P1 showed higher binding capacity (Cp) and imprinting factor (IF) for acifluorfen in aqueous media. Scatchard plot analysis revealed that two classes of binding sites were formed in the imprinted polymer P1 with dissociation constants of 0.435 an...

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