Isomeric triarylamine-ferrocene mixed-valence systems: Syntheses, structural-(spectro)electrochemical analysis, and theoretical calculations

首页 > 成果 > 详情

认领

导出

Link by DOI

反馈

作者信息关键词期刊信息基础信息归属信息摘要

成果类型：

期刊论文

作者：

Ou, Ya-Ping;Zhang, Qian;Yang, Xiaofei;Cao, Na;Jiang, Penghui;...

通讯作者：

Liu, Sheng Hua

作者机构：

[Ou, Ya-Ping; Cao, Na; Jiang, Penghui; Zhang, Qian] Hengyang Normal Univ, Coll Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.

[Ou, Ya-Ping; Cao, Na; Jiang, Penghui; Zhang, Qian] Hengyang Normal Univ, Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Peoples R China.

[Ou, Ya-Ping; Cao, Na; Jiang, Penghui; Zhang, Qian] Hengyang Normal Univ, Key Lab Funct Organometall Mat Hunan Prov Coll, Hengyang 421008, Hunan, Peoples R China.

[Ou, Ya-Ping; Cao, Na; Jiang, Penghui; Zhang, Qian] Hunan Engn Res Ctr Monitoring & Treatment Heavy M, Hengyang 421001, Hunan, Peoples R China.

[Ou, Ya-Ping; Liu, Sheng Hua; Yang, Xiaofei] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.

通讯机构：

[Liu, Sheng Hua] C

Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.

语种：

英文

关键词：

Ferrocene;Mixed-valence complexes;Spectroelectrochemistry;Theoretical calculations;Triarylamine

期刊：

Inorganica Chimica Acta

ISSN：

0020-1693

年：

2021

卷：

528

页码：

120603

DOI：

10.1016/j.ica.2021.120603

基金类别：

The authors acknowledge the financial support from National Natural Science Foundation of China ( 21602049 ), the Natural Science Foundation of Hunan Province, China (Nos. 2017JJ3004 , 2021JJ30058 ), the Opening Subjects of Hunan Province Key Laboratory of Functional Metal-Organic Compounds (No. MO19K04), the Aid Programs for Technology Innovative Team, Key Discipline in Education Department of Hunan Province and Functional Metal-Organic Compounds of Hunan Science and Technology Innovation Team, and the Support Plan for Talents in Hengyang Normal University.

机构署名：

本校为第一机构

院系归属：

化学与材料科学学院

摘要：

Six novel triarylamine (TAA)–ferrocenyl conjugates (1–6) were prepared and characterized using molecular spectroscopic and crystallographic methods. Different species with a corresponding valences of 1n+−6n+ (n = 0, 1) were investigated using cyclic voltammetry, UV–Vis–NIR spectroelectrochemistry, and quantum–chemical calculations. Electrochemical analysis of two groups of isomeric complexes (1–2) and complexes (3–6) revealed that the effective distance between redox–active ferrocenyl and TAA remarkably influenced the redox potential d...

反馈

产权有误：本人成果被他人认领

数据有误：数据基本信息有误

归属有误：成果的院系归属、机构署名归属有误

其他原因：

验证码：

看不清楚，换一个

确定

取消

成果认领

标题：

用户	作者	通讯作者	--
	请选择	请选择	--

确定

取消

Isomeric triarylamine-ferrocene mixed-valence systems: Syntheses, structural-(spectro)electrochemical analysis, and theoretical calculations

反馈

成果认领

提示

该栏目需要登录且有访问权限才可以访问