Modification of mesoporous silica with molecular imprinting technology: A facile strategy for achieving rapid and specific adsorption

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成果类型：

期刊论文

作者：

Xu, Zhifeng*;Deng, Peihong;Li, Junhua;Tang, Siping;Cui, Ying

通讯作者：

Xu, Zhifeng

作者机构：

[Tang, Siping; Deng, Peihong; Xu, Zhifeng; Li, Junhua; Cui, Ying] Hengyang Normal Univ, Coll Chem & Mat Sci, Key Lab Funct Organometall Mat Hunan Prov Univ, Hengyang 421008, Peoples R China.

[Xu, Zhifeng] Hengyang Normal Univ, Coll Chem & Mat Sci, Hengyang 421008, Peoples R China.

通讯机构：

[Xu, Zhifeng] H

Hengyang Normal Univ, Coll Chem & Mat Sci, Hengyang 421008, Peoples R China.

语种：

英文

关键词：

Binding energy;Biosynthesis;Extraction;Fourier transform infrared spectroscopy;Gravimetric analysis;High resolution transmission electron microscopy;Hydrocarbons;Mass transfer;Molecular modeling;Monomers;Organic polymers;Phase separation;Polymerization;Silica;Thermogravimetric analysis;Transmission electron microscopy;2 ,4-dichlorophenoxyacetic acid;Click reaction;Mesoporous Silica;Molecular imprinting;SBA-15;Mesoporous materials;2,4 dichlorophenoxyacetic acid;beta cyclodextrin;beta cyclodextrin derivative;nitrogen;SBA-15;silicon dioxide;adsorption;chemistry;kinetics;molecular imprinting;porosity;procedures;proton nuclear magnetic resonance;solid phase extraction;synthesis;thermogravimetry;ultraviolet spectrophotometry;X ray diffraction;2,4-Dichlorophenoxyacetic Acid;Adsorption;beta-Cyclodextrins;Kinetics;Molecular Imprinting;Nitrogen;Porosity;Proton Magnetic Resonance Spectroscopy;Silicon Dioxide;Solid Phase Extraction;Spectrophotometry, Ultraviolet;Thermogravimetry;X-Ray Diffraction

期刊：

Materials Science and Engineering C: Materials for Biological Applications

ISSN：

0928-4931

年：

2019

卷：

页码：

684-693

DOI：

10.1016/j.msec.2018.10.032

基金类别：

This work was financially supported by the National Natural Science Foundation of China (No. 21472038 and 21505035), the Natural Science Foundation of Hunan Province (No. 2017JJ2007, 2016JJ3028), the Open Fund of Key Laboratory of Functional Organometallic Materials of Ordinary University in Hunan Province (No. 17K013), and the Aid Programs for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province. This work was financially supported by the National Natural Science Foundation of China (No. 21472038 and 21505035 ), the Natural Science Foundation of Hunan Province (No. 2017JJ2007 , 2016JJ3028 ), the Open Fund of Key Laboratory of Functional Organometallic Materials of Ordinary University in Hunan Province (No. 17K013 ), and the Aid Programs for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province .

机构署名：

本校为第一且通讯机构

院系归属：

化学与材料科学学院

摘要：

In order to improve the diffusion kinetics of molecularly imprinted materials (MIMs), applying imprinting technology to mesoporous materials is a promising strategy. In the present study, an imprinting approach based on the combination of mesoporous silica materials and molecular imprinting technology is reported. Molecularly imprinted material (MIM) for 2,4-dichlorophenoxyacetic acid (2,4-D) was prepared by using 2,4-D as the template molecule, alkyne-modified β-cyclodextrin and propargyl amine as the combinatorial functional monomers and SBA...

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Modification of mesoporous silica with molecular imprinting technology: A facile strategy for achieving rapid and specific adsorption

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