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Modulating Oxygen Vacancies via Sputtered WOx Top Electrodes for Enhanced Ferroelectricity and Improved Fatigue Stability in HZO Thin Films

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成果类型:
期刊论文
作者:
Wenqi Sun;Fuling Wu;Chao Ye;Shibing Xiao;Huiting Sui;...
通讯作者:
Huajun Sun
作者机构:
School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, People’s Republic of China
State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, People’s Republic of China
Advanced Ceramics Institute of Zibo New & High–Tech Industrial Development Zone, Zibo 255000, People’s Republic of China
[Xiaofang Liu] School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, Wuhan 430070, People’s Republic of China
[Shibing Xiao] College of Chemistry and Material Science, Hengyang Normal University, Hengyang 421008, PR China
通讯机构:
[Huajun Sun] S
School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, People’s Republic of China<&wdkj&>State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, People’s Republic of China<&wdkj&>Advanced Ceramics Institute of Zibo New & High–Tech Industrial Development Zone, Zibo 255000, People’s Republic of China
语种:
英文
期刊:
Ceramics International
ISSN:
0272-8842
年:
2025
基金类别:
Acknowledgements This work was supported by the National Natural Science Foundation of China (Grant No. U1806221), and Instruction & Development Project for National Innovation Demonstration Zone of Shandong Province (Nos. 2018ZCQZB01, 2019ZCQZB03).
机构署名:
本校为其他机构
院系归属:
化学与材料科学学院
摘要:
Owing to the inverse size effect and CMOS process compatibility of ferroelectric Hf 0.5 Zr 0.5 O 2 (HZO) films, they have emerged as one of the most promising candidates for next-generation non-volatile memory devices. However, the presence of excessive oxygen vacancies (V O ) within the film or at the film–electrode interface results in degraded ferroelectricity, elevated coercive fields, and poor fatigue endurance, thereby impeding the progress toward practical device applications. Currently, employing oxide materials as oxygen donors to sup...

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