Room-temperature Cu-catalyzed N-arylation of aliphatic amines in neat water

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成果类型：

期刊论文

作者：

Wang, Deping*;Zheng, Yanwen;Yang, Min;Zhang, Fuxing;Mao, Fangfang;...

通讯作者：

Wang, Deping;Xia, Xiaohong

作者机构：

[Yu, Jiangxi; Zhang, Fuxing; Mao, Fangfang; Wang, Deping; Zheng, Yanwen] Hengyang Normal Univ, Coll Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.

[Yang, Min; Xia, Xiaohong] Hunan Univ, Coll Mat Sci & Engn, Changsha 410082, Hunan, Peoples R China.

通讯机构：

[Wang, Deping; Xia, Xiaohong] H

Hengyang Normal Univ, Coll Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.

Hunan Univ, Coll Mat Sci & Engn, Changsha 410082, Hunan, Peoples R China.

语种：

英文

关键词：

Amines;Catalysis;Chemical reactions;Potash;Potassium compounds;Aliphatic amines;Copper catalyzed;N-arylations;Aromatic compounds

期刊：

Organic & Biomolecular Chemistry

ISSN：

1477-0520

年：

2017

卷：

期：

页码：

8009-8012

DOI：

10.1039/c7ob02126g

基金类别：

The authors thank the National Natural Science Foundation of China (No. 21202041 and 51402101), the Natural Science Foundation of Hunan Province (No. 2017JJ2008), the Aid Programs for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province, and the Key Discipline of Hunan Province for their financial support.

机构署名：

本校为第一且通讯机构

院系归属：

化学与材料科学学院

摘要：

A room-temperature and PTC-free copper-catalyzed N-arylation of aliphatic amines in neat water has been developed. Using a combination of CuI and 6,7-dihydroquinolin-8(5H)-one oxime as the catalyst and KOH as the base, a wide range of aliphatic amines are arylated with various aryl and heteroaryl halides to give the co...

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Room-temperature Cu-catalyzed N-arylation of aliphatic amines in neat water

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