[Liu, Jinlong; Luo, Ziyu; Li, Jie; Su, Kanda; Zhang, Xinxin; Chen, Xiangxiong; Qian, Dong; Wang, Bowen] Cent South Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China.
[Li, Junhua] Hengyang Normal Univ, Coll Chem & Mat Sci, Hengyang 421008, Peoples R China.
通讯机构:
[Dong Qian; Junhua Li; Jinlong Liu] C
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China<&wdkj&>College of Chemistry and Material Science, Hengyang Normal University, Hengyang 421008, China
National Natural Science Foundation of China; Central South University; [51874359]; [52103354]; [202045020]
机构署名:
本校为其他机构
院系归属:
化学与材料科学学院
摘要:
Herein, an extremely simple l-alanine-assisted pyrolysis method was proposed for the construction of a novel hierarchically porous hybrid of Fe(4)N-Fe supported on N-doped carbon nanobelts and Ketjen black carbon (denoted as Fe(4)N-Fe@N-C/N-KB). It has been found that the participation of l-alanine in pyrolysis can dramatically increase the total pyridinic-N/graphitic-N content in Fe(4)N-Fe@N-C/N-KB, which is peculiarly conducive to the enhancement of ORR performance. The in-site formation of the Fe(4)N-Fe heterojunction via the thermal reduction and decomposition of Fe(3)N as well as the intr...