期刊论文

Synthesis,Structures and Properties of Tris(o-methylbenzyl) tin Thiosalicylate and Di(m-fluorobenzyl) tin Thiosalicylate

中文

应用化学

1000-0518

2017

34

2

163-171

10.11944/j.issn.1000-0518.2017.02.160183

(15K017,14K014,13K105):Hu'nan Province University Innovation Platform of Open Fund Project (13JJ3112):Hu'nan Provincial Natural Science Foundation of China (2014NK3086):Scientific & Technological Projects of Hu'nan Province :Aid Programs for Science and Technology Innovative Research Team in Higher Educational Institutions of Hu'nan Province and the Key Discipline of Hu'nan Province,and Project Funding for Research and Innovation Experiment of University Students in Hu'nan Province,the Scientific Research Fund of Hu'nan (13JJ3112):湖南省自然科学基金 (2014NK3086):湖南省科技计划 (15C0199,15CO200):湖南省重点学科基金、湖南省高校科技创新团队支持计划和湖南省大学生研究性学习和创新性实验项目,湖南省教育厅基金

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合成了三(邻甲基苄基)锡硫代水杨酸酯配合物(1)和一维链状二(间氟苄基)锡硫代水杨酸酯配合物(2),经元素分析、IR、NMR、X射线衍射等技术手段表征了其结构。配合物1属三斜晶系,空间群Pi,晶体学参数a = 1. 00221(5) nm,b = 1. 48934(8) nm,c = 1. 71789(9) nm,α = 78. 3120(10) °,β = 85. 6560(10) °, γ = 80. 2580(10) °,V = 2. 4725(2) nm~3,Z = 2,D_c = 1. 371 g /cm~3,μ(MoKα) = 10. 91 cm~(-1),F(000) = 1040, R_1 = 0. 0439,wR_2 = 0. 1119。配合物2属单斜晶系,空间群为P2_1 /n,晶体学参数: a = 1. 17827(5) nm, b = 2. 11945(9) nm,c = 1. 55970(7) nm,β = 93. 4510(10) °,V = 3...

Tris(o-methylbenzyl) tin thiosalicylate(1) and di(m-fluorobenzyl) tin thiosalicylate(2) have been synthesized. Crystal structures of the complexes were determined by X-ray diffraction. Crystal 1 belongs to the triclinic space group Pi with a = 1. 00221(5) nm, b = 1. 48934(8) nm, c = 1. 71789(9) nm, α = 78. 3120(10) °, β = 85. 6560(10) °, γ = 80. 2580(10) °, V = 2. 4725(2) nm~3, Z = 2, D_c = 1. 371 g /cm~3,μ(MoKα) = 10. 91 cm - 1,F(000) = 1040,R_1 = 0. 0439,wR_2 = 0. 1119. Crystal 2 belongs to the monoclinic space group P2_1 /n with a = ...