Understanding water reaction pathways to control the hydrolytic reactivity of a Zn metal-organic framework

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成果类型：

期刊论文

作者：

Chen, Shoushun;Zhang, Zelin;Chen, Wei;Lucier, Bryan E. G.;Chen, Mansheng;...

通讯作者：

Chen, SS;Lei, DS;Huang, YN

作者机构：

[Zhu, Haihong; Chen, Shoushun; Chen, SS] Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou Magnet Resonance Ctr, Frontiers Sci Ctr Rare Isotopes, Lanzhou 730000, Peoples R China.

[Zhang, Zelin; Lei, Dongsheng; Lei, DS] Lanzhou Univ, Electron Microscopy Ctr, Sch Phys Sci & Technol, Lanzhou 730000, Peoples R China.

[Zheng, Anmin; Chen, Wei] Chinese Acad Sci, Innovat Acad Precis Measurement Sci & Technol, Wuhan 430071, Peoples R China.

[Huang, Yining; Chen, Mansheng; Lucier, Bryan E. G.; Zhang, Wanli] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada.

[Chen, Mansheng] Hengyang Normal Univ, Coll Chem & Mat Sci, Key Lab Funct Organometall Mat, Hengyang 421008, Hunan, Peoples R China.

通讯机构：

[Chen, SS ; Lei, DS ] L

[Huang, YN ] U

Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou Magnet Resonance Ctr, Frontiers Sci Ctr Rare Isotopes, Lanzhou 730000, Peoples R China.

Lanzhou Univ, Electron Microscopy Ctr, Sch Phys Sci & Technol, Lanzhou 730000, Peoples R China.

Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada.

语种：

英文

期刊：

Nature Communications

ISSN：

2041-1723

年：

2024

卷：

期：

页码：

10776

DOI：

10.1038/s41467-024-54493-7

基金类别：

National Natural Science Foundation of China (National Science Foundation of China) [22105091, 32171300]; National Natural Science Foundation of China [lzujbky-2021-sp26, lzujbky-2021-ct05]; Fundamental Research Funds for the Central Universities; Natural Sciences and Engineering Research Council of Canada [2024040701010058]; Natural Science Foundation of Wuhan [DMR-2128556]; National Science Foundation (NSF); State of Florida

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本校为其他机构

院系归属：

化学与材料科学学院

摘要：

Metal-organic frameworks (MOFs) are a class of porous materials that are of topical interest for their utility in water-related applications. Nevertheless, molecular-level insight into water-MOF interactions and MOF hydrolytic reactivity remains understudied. Herein, we report two hydrolytic pathways leading to either structural stability or framework decomposition of a MOF (ZnMOF-1). The two distinct ZnMOF-1 water reaction pathways are linked to the diffusion rate of incorporated guest dimethylformamide (DMF) molecules: slow diffusion of DMF triggers evolution of the initial MOF into a water-...

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Understanding water reaction pathways to control the hydrolytic reactivity of a Zn metal-organic framework

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