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An efficient pH-universal non-noble hydrogen-evolving electrocatalyst from transition metal phosphides-based heterostructures

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成果类型:
期刊论文
作者:
Mo, Yuxue;Ni, Yifan;Li, Xin;Pan, Rongwu;Tang, Yuxiang;...
通讯作者:
Tan, YL;Yu, F
作者机构:
[Tan, Yanliang; Mo, Yuxue; Deng, Yanhong; Tang, Yuxiang; Xiao, Binbin; Tan, YL; Li, Xin] Hengyang Normal Univ, Coll Phys & Elect Engn, Henghua Rd 16, Hengyang 421002, Hunan, Peoples R China.
[Mo, Yuxue; Ni, Yifan; Yu, Fang] Hunan Normal Univ, Minist Educ, Key Lab Low Dimens Quantum Struct & Quantum Contro, Key Lab Matter Microstruct & Funct Hunan Prov, Changsha 410081, Peoples R China.
[Pan, Rongwu] Hunan Shengli High tech Energy Technol Co Ltd, Yongzhou 425000, Peoples R China.
[Mo, Yuxue] Hunan Prov Key Lab Intelligent Informat Proc & App, Hengyang 421002, Peoples R China.
通讯机构:
[Tan, YL ; Yu, F ] H
Hengyang Normal Univ, Coll Phys & Elect Engn, Henghua Rd 16, Hengyang 421002, Hunan, Peoples R China.
Hunan Normal Univ, Minist Educ, Key Lab Low Dimens Quantum Struct & Quantum Contro, Key Lab Matter Microstruct & Funct Hunan Prov, Changsha 410081, Peoples R China.
语种:
英文
关键词:
Alkalinity;Catalyst activity;Crystal structure;Current density;Electrolytes;Hydrogen production;Iron compounds;pH;Phosphorus compounds;Precious metals;Acidic electrolytes;Alkaline electrolytes;All-ph electrocatalyst;Hydrogen evolution reactions;Hydrogen-evolution;Large current density;Metal phosphides;Transition metal phosphide;Water splitting;Wide pH range;Electrocatalysts
期刊:
International Journal of Hydrogen Energy
ISSN:
0360-3199
年:
2023
卷:
48
期:
80
页码:
31101-31109
基金类别:
This project was financially supported by the funds from National Science Foundation of China , China ( No. 12074116 , No. 52172197 and No. U1865207 ), PhD Start-up Foundation of Hengyang Normal University, China ( 2020QD23 ), and Scientific Research Fund of Hunan Provincial Education Department , China ( No. 20A062 and No. 21C0550 ). This work was also supported by the key laboratory of optoelectronic control and detection technology of university of Hunan Province , China and the science and technology innovation Program of Hunan Province , China (No. 2016TP1020 ).
机构署名:
本校为第一且通讯机构
院系归属:
物理与电子工程学院
摘要:
The catalytic hydrogen-evolving activities of noble-metal-free catalysts can be greatly enhanced by the crystal structure and components through appropriate interface engineering with anion and cation doped into the catalytic materials. However, the developments of inexpensive electrocatalysts suffer from activity incompatibility with different water sources over a wide pH range. Here we report a promising HER electrocatalyst by hybridizing iron phosphide (FeP4) nanoparticles with highly conductive CoP nanowire arrays (abbreviated as FeP4/CoP) ...

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