期刊论文

Yu, Jiangxi;Li, Jinheng

英文

中国科学：化学英文版

1674-7291

2016

59

2

184-189

10.1007/s11426-015-5529-0

This work was supported by the National Natural Science Foundation of China （21402046, 21172060, 21472039）, and the Fundamental Research Funds for the Central Universities. Dr. Renjie Song also thanks the Fundamental Research Funds for the Central Universities.

本校为通讯机构

A new radical-mediated method for the synthesis of 1-(2-(1,2-diarylvinyl)phenyl)ethan-1-ones by the redox hydroarylation of o-(hydroxyalkyl)arylalkynes with arylsulfonyl chlorides is described. This visible light catalysis method proceeds via a sequence of the radical addition of aryl group across the C-C triple bond, protonation and redox reaction, and represents a new redox transformation ...

为 1-(2-(1,2-diarylvinyl ) 苯基) 的合成的一个新调停激进分子的方法由 o-(hydroxyalkyl ) 的氧化还原作用 hydroarylation 的 ethan-1-ones 有 arylsulfonyl 氯化物的 arylalkynes 被描述。这个可见轻催化作用方法越过 C-C 三倍的契约， protonation 和氧化还原作用反应经由芳基组的激进的增加的一个序列继续，并且代表一个附近的氢氧根组指导的新氧化还原作用转变反应。