Facile syntheses of bimetallic Prussian blue analogues (KxM[Fe(CN)6]·nH2O, M=Ni, Co, and Mn) for electrochemical determination of toxic 2-nitrophenol

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成果类型：

期刊论文

作者：

Li, Junhua;He, Lingzhi;Jiang, Jianbo;Xu, Zhifeng;Liu, Mengqin;...

通讯作者：

Qian, Dong

作者机构：

[Liu, Xing; Liu, Mengqin; Xu, Zhifeng; Li, Junhua; He, Lingzhi] Hengyang Normal Univ, Hunan Prov Univ Key Lab Funct Organometall Mat, Coll Chem & Mat Sci, Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Peoples R China.

[Li, Junhua; Qian, Dong] Cent South Univ, Coll Chem & Chem Engn, Hunan Prov Key Lab Efficient & Clean Utilizat Man, Changsha 410083, Peoples R China.

[He, Lingzhi] Hunan Polytech Environm & Biol, Sch Med, Hengyang 421008, Peoples R China.

[Jiang, Jianbo] Jishou Univ, Coll Chem & Chem Engn, Jishou 416000, Peoples R China.

[Tong, Haixia] Changsha Univ Sci & Technol, Inst Chem & Biol Engn, Changsha 410114, Peoples R China.

通讯机构：

[Qian, Dong] C

Cent South Univ, Coll Chem & Chem Engn, Hunan Prov Key Lab Efficient & Clean Utilizat Man, Changsha 410083, Peoples R China.

语种：

英文

关键词：

Prussian blue analogues;Synthesis;Electrochemical determination;2-Nitrophenol

期刊：

Electrochimica Acta

ISSN：

0013-4686

年：

2020

卷：

353

页码：

136579

DOI：

10.1016/j.electacta.2020.136579

基金类别：

National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21505035, 51874359, 21171174, 21472038, 21603065]; Provincial Natural Science Foundation of HunanNatural Science Foundation of Hunan Province [2020JJ4149, 2020JJ4506, 2017JJ2007]; Scientific Research Projects of Education Department of Hunan Province [18A336, 19K011]; Hunan Provincial Science and Technology Plan Project [2017TP1001]; Hengyang City Science and Technology Plan Project [2019jhzx0741]; Environmental Monitoring and Evaluation Center of Hengyang Normal University [KYJG1803]; Opening Subjects of Key Laboratory of Functional Metal-Organic Compounds of Hunan Province [MO19K09]

机构署名：

本校为第一机构

院系归属：

化学与材料科学学院

摘要：

In this work, three kinds of bimetallic Prussian blue analogues (PBAs), i.e. KxNi [Fe(CN)(6)]center dot nH(2)O (NiFe-PBA), KxCo [Fe(CN)(6)]center dot nH(2)O (CoFe-PBA), and KxMn [Fe(CN)(6)]center dot nH(2)O (MnFe-PBA), were synthesized by a simple precipitation method under identical conditions. Their chemical compositions, structures, morphologies, valences of transition metals, and electrochemical sensing performances for 2-nitrophenol (2-NP) are examined in details. It is found that all the prepared PBAs hold face-centered-cubic structures with near perfect cube morphologies for NiFe-PBA an...

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Facile syntheses of bimetallic Prussian blue analogues (KxM[Fe(CN)6]·nH2O, M=Ni, Co, and Mn) for electrochemical determination of toxic 2-nitrophenol

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