The liquorice acid was extracted by an improved method. The complex salt of liquorice acid with amino acid was synthesized in 70 % ethanol solution at pH ≈ 5 and 60 ℃. The salts were analyzed by elementaly analysis, IR, UV-Vis and thermogravimetric methods.Their formula are (C6H15N2O2)2·HG, (C6H10N3O2)2·HG and (C6H15N4O2)2·HG respkectively. The property of the complex salt was tested. The work is useful for further study on the e...