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Long-Lived and Highly Efficient TADF-PhOLED with "(A)(n)-D-(A)(n)" Structured Terpyridine Electron-Transporting Material

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成果类型:
期刊论文
作者:
Bian, Mengying;Zhang, Dongdong;Wang, Yuanxun;Chung, Yao-Hsien;Liu, Yang;...
通讯作者:
Xiao, Lixin;Liu, Zhiwei
作者机构:
[Chung, Yao-Hsien; Bian, Mengying; Ting, Hungkit; Xiao, Lixin; Chen, Zhijian] Peking Univ, State Key Lab Mesoscop Phys, Beijing 100871, Peoples R China.
[Chung, Yao-Hsien; Bian, Mengying; Ting, Hungkit; Xiao, Lixin; Chen, Zhijian] Peking Univ, Dept Phys, Beijing 100871, Peoples R China.
[Zhang, Dongdong; Duan, Lian] Tsinghua Univ, Minist Educ, Dept Chem, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China.
[Wang, Yuanxun] Valiant Corp, Yantai 264006, Shandong, Peoples R China.
[Liu, Zhiwei; Liu, Yang; Bian, Zuqiang] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China.
通讯机构:
[Xiao, Lixin; Liu, Zhiwei] P
[Xiao, Lixin] H
Peking Univ, State Key Lab Mesoscop Phys, Beijing 100871, Peoples R China.
Peking Univ, Dept Phys, Beijing 100871, Peoples R China.
Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China.
语种:
英文
关键词:
electron-transporting;long lifetime;organic light-emitting diodes;phosphorescence;terpyridine;thermally activated delayed fluorescence
期刊:
Advanced Functional Materials
ISSN:
1616-301X
年:
2018
卷:
28
期:
28
页码:
1800429-
基金类别:
This study was financially supported in part by the National Key R&D Program of China (No. 2016YFB0401000) and by NSFC (Grant Nos. 61575005, 61775004, 11574009, and U1605244).
机构署名:
本校为通讯机构
院系归属:
物理与电子工程学院
摘要:
AbstractThe electron‐transporting material (ETM) is one of the key factors to determine the efficiency and stability of organic light‐emitting diodes (OLEDs). A novel ETM with a “(Acceptor)n–Donor–(Acceptor)n” (“(A)n–D–(A)n”) structure, 2,7‐di([2,2′:6′,2″‐terpyridin]‐4′‐yl)‐9,9′‐spirobifluorene (27‐TPSF), is synthesized by combining electron‐withdrawing terpyridine (TPY) moieties and rigid twisted spirobifluorene, in which the TPY moieties facilitate electron transport and injection while the spirobifluorene moiety ensure...

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