期刊论文

Liang, FP

中文

无机化学学报

1001-4861

2005

21

5

689-692

10.3321/j.issn:1001-4861.2005.05.014

广西自然科学基金资助项目（No.0229004）。；

本校为其他机构

近年来,设计与合成金属锰羧酸配合物引起了化学研究者广泛的兴趣,主要原因是它们不仅可以用来研究化合物中金属离子间的磁相互作用,且可望开发一类新型分子磁性材料[1～4].另外,多聚锰配合物还可以用作光合作用放氧中心复合物的模型物[5～7].……

A one-dimensional double-chain coordination polymer [Mn(phen)(tsgluo)] was synthesized in a mixed solution and its crystal structure was determined by X-ray diffraction method. It crystallizes in orthorhombic system with space group P2(1)2(1)2(1). The crystal data are: a=0.53078(17) nm, b = 1.7239(5) nm, c =2.4569(8) nm, Z=4, μ=0.729 mm(-1), D-c=1.579 gˆ cm(-3), V=2.2481(12) nm(3), R-1=0.0331, ω R-2=0.0789. In the title complex, each Mn(II) ion presents a octahedral geometry with the coordination of two nitrogen atoms from 1,10-phenanthroline and four oxygen atoms from three diff...