The title complex [^nBuSn（O）（tsglyO）]6·6CHCl3 （tsglyO=N-p-tolysulfonyl-glycinate monoanion） was synthesized by the reaction of ^nBuSn（O）OH with N-p-tolysulfonyl-glycine in 1：1 molar ratio. The complex was characterized by IR, ^1H NMR spectra and elemental analysis. The crystal structure was determined by X-ray diffraction method. It crystallizes in rhombohedral system with space group R3. The crystal data are： a=b=2.738 7（4） nm, c= 1.446 5（4） nm, α=β=90°, γ=120°, Z=6, Dc=1.726 g·cm^-3, F（000）=4 878, V=9.396（3） nm^3, R1=...
