期刊论文

Kuang Dai-Zhi

英文

无机化学学报

1001-4861

2007

23

1

145-148

10.3321/j.issn:1001-4861.2007.01.027

湖南省基础研究项目（No.03JZY3036）； 衡阳师范学院科学基金青年项目资助（No.2006A15）；

本校为第一且通讯机构

The title compound, [Mn(2,4,6-TMBA)2(H2O) 3]n·2nH2O (1), where 2,4,6-TMBA=2,4,6-trimethylbenzoic acid, was synthesized and its crystal structure was determined by X-ray diffraction analysis. The crystal is of monoclinic, space group C2/c with a=2.9299(6) nm, 6=1.0364(2) nm, c=8.22204(17) nm, V=2.4947(9) nm3, Z=4, M=471.40, Dc=1.255 g·cm-3, μ=0.571 mm-1, F(000)=996, R int=0.0294, R=0.0376 and wR=0.0949. The Mn atoms are octahedrally coordinated by two O atoms of two ligands and four O atoms of water. The carboxyl group coordinates to Mn(II) i...