期刊论文

Zhang Chun-Hua

中文

无机化学学报

1001-4861

2008

24

9

1519-1522

10.3321/j.issn:1001-4861.2008.09.028

湖南省自然科学基金资助项目（No05JJ30016）； 湖南省教育厅重点项目（No07A013）； 湖南省高校“十一五”重点建设学科资助项目；

本校为第一且通讯机构

A dinuclear manganese(II) complex, [Mn-2(L-1)(2)(phen)(4)]center dot(ClO4)(2) (1), has been synthesized and structurally characterized (HL1=2,6-dichlorobenzoic acid, phen=1,10-phenanthroline). It crystallizes in triclinic system, space group P1 with a=1.1123(4) nm, b=1.378 2(4) nm, c=2.085 7(3) nm, alpha=93.768(2)degrees, beta=90.606(10)degrees, gamma=95.606(3)degrees, V=3.174 8(15) nm(3), Z=2, C62H38Cl6Mn2N8O12, M-r=1 409.58, D-c=1.475 g.cm(-3), mu=0.718 mm(-1), F(000)=1 428, R= 0.064 3, wR =0.138 3. In the crystal the manganese atom is six-coordinated by two oxygen atoms from two different 2...