期刊论文

Yang Ying-Qun

中文

无机化学学报

1001-4861

2008

24

9

1531-1534

10.3321/j.issn:1001-4861.2008.09.031

湖南省重点建设学科资助项目 衡阳师范学院青年骨干基金项目（No.2006）.

本校为第一且通讯机构

近年来,人们对锰配合物的研究引起极大兴趣,这主要归因于锰的配合物有其生物功能.生物体内的过氧氢化酶、过氧歧化酶和放氧复合物,这3种酶的作用都涉及锰(Ⅱ)离子,锰离子参与了生物体内的氧化还原反应,是绿色植物的第二类光合系统的活性中心[1].

A complex [Mn (2,4-DAA)(2) (4,4'-bipy)](n) with 2,4-dichlorophenoxy acetic acid and 4,4'-bipy has been synthesized and characterized. It crystallizes in the monoclinic space group C2/c with a=2.307 8(6) nm, b=1.164 3(3) nm, c=0.970 9(3) nm, beta=96.249(5)degrees, V=2.593 2(12) nm(3), D-c=1.668 g.cm(-3), Z=4, F(000)=1 316, Final GooF=1.032, R-1=0.046 1, wR(2)=0.110 2. The crystal structure shows that the complex forms a 2D layer structure by bi-dentate bridging 2,4-dichlorophenoxy acetic acid groups and 4,4'-bipy molecules. The manganese (II) ion is coordinated with four oxygen atoms from four ...