期刊论文

Chen Zhi-Min

英文

无机化学学报

1001-4861

2008

24

11

1907-1911

10.3321/j.issn:1001-4861.2008.11.032

湖南省教育厅资助项目（No.06A009） 湖南省重点学科建设资助项目.安徽省教育厅资助项目（No.KJ20078231） 安徽省高等学校青年教师资助项目（No.2007jq1143） 阜阳师范学院资助项目（No.FJK200741）.

本校为第一且通讯机构

A Manganese(II) polymer {[Mn(bpdc)(bipy)(H2O)]·4.5H 2O}n has been synthesized (bpdc=2,2-bipyridine-3,3- dicarboxylate,bipy=4,4-bipyridine) and characterized by IR, UV, elemental analysis and X-ray crystal structure determination. It crystallizes in Monoclinic system, space group P2/n with a=1.010 13(8) nm, b=1.164 66(9) nm, c=2.147 40(16) nm, β=98.2220(10)°, V=2.500 4(3) nm3, Z=4, Dc=1.467 g·cm-3, F(000)=1 144, R1=0.049 0, wR2=0.141 2. The crystal structure shows that the Mn2+ ions have octahedral coordination geometry with two coordination...