期刊论文

Li Wei

中文

无机化学学报

1001-4861

2009

25

5

934-937

10.3321/j.issn:1001-4861.2009.05.032

湖南省科技厅重点项目（No.2008FJ3023）； 衡阳师范学院青年骨干基金项目（2006）； 湖南省重点建设学科资助项目；

本校为第一且通讯机构

配位聚合物由于其在分子识别、催化、光电性质和磁性等方面表现出的独特性能,近年来已引起人们的极大关注[1-3].

One double chains nickel(II) coordination polymer has been synthesized and characterized in the solvent mixture of water and methanol with 3,5-dimethylbenzole acid, 4,4'-bipyridine and nickel perchlorate anhydrous. Crystal data for this complex: Triclinic, space group P (1) over bar, a=1.13449(12) nm, b=1.137 81(12) urn, c=1.238 25(13) rim; alpha=100.374 0(10)degrees, beta=109.481 0(10)degrees, gamma=101.403 0(10)degrees, V=1.423 8(3) nm(3), D-c=1.314 g.cm(-3), Z=1, F(000)= 592, final GooF=1.029, R-1=0.0396, wR(2)=0.1064. The complex involves two solvent molecules, two waters or two methanols....