期刊论文

Tan Xiong-Wen

中文

无机化学学报

1001-4861

2009

25

10

1877-1881

10.3321/j.issn:1001-4861.2009.10.030

本校为第一且通讯机构

One dimensional chain cobalt coordination polymer has been synthesized with malic acid and cobalt (Ⅱ) chloride anhydrous,and characterized by the element analysis,IR,TGA and single crystal X-ray diffraction structure analysis.The title complex crystallizes in monoclinic system with space group P21,a=0.575 61(9) nm,b= 0.905 86(14) nm,c=0.841 02(13) nm,β=105.350(2)°;V=0.422 88(11) nm3,Z=2,Dc=1.924 Mg.m-3,μ=2.044 mm-1,F(000)=250,and final R1=0.029 3,wR2=0.074 2.The crystal structure shows that the ...更多cobalt ion is coordinated with four oxy...

One dimensional chain cobalt coordination polymer has been synthesized with malie acid and cobalt(II) chloride anhydrous, and characterized by the element analysis, IR, TGA and single crystal X-ray diffraction structure analysis. The title complex crystallizes in monoclinic system with space group P2 1, a=0.575 61(9) nm, b= 0.905 86(14) nm, c=0.841 02(13) nm, β=105.350(2) °; V =0.422 88(11) nm 3, Z=2, D c, =1.924 Mg•m -3, μ=2.044 mm -1, F(000)=250, and final R 1=0.029 3, wR 2=0.074 2. The crystal structure shows that the cobalt ion is coord...