期刊论文

Wei, Li

中文

无机化学学报

1001-4861

2009

25

6

1106-1109

10.3321/j.issn:1001-4861.2009.06.029

湖南省科技厅项目（No.2008FJ3023）； 衡阳师范学院青年骨干基金项目（2006）； 湖南省重点建设学科资助项目；

本校为第一且通讯机构

由简单小分子配体和金属镉离子形成的配合物通过氢键可以构筑具有高级有序结构的分子聚集体,这些分子聚集体在制备具有磁性、生物活性、光学性质和催化性能等新材料方面有着潜在的应用前景.

A seven-coordinate dimmer has been synthesized with 5-oxo-4-oxa-tricyclo[4. 2.1.0]nonane-9-carboxylic acid and 1,10-phenanthroline. The crystal structure was determined by single-crystal X-ray structural analysis. The crystal belongs to a monoclinic system, space group P2 1ln, with α=1.552 08(12) nm, b = 1.065 52(8) nm, c=1.626 57 (12) nm, β=100.100 (10)°, V=2.648 3 (3) nm 3, D c= 1.643 gcm- 3, Z=2, F (000)= 1 328, Final GooF=1.026, R l= 0.026 2, wR 2=0.059 2. The crystal structure shows that the cadmium ion is coordinated with five oxygen a...