期刊论文

Li Wei

中文

无机化学学报

1001-4861

2009

25

2

369-372

10.3321/j.issn:1001-4861.2009.02.032

湖南省科技厅项目（No.2008FJ3023）； 衡阳师范学院青年骨干基金项目（2006）； 湖南省重点建设学科资助项目；

本校为第一且通讯机构

具有多维高度有序框架结构的配位聚合物由-于其在分子识别和催化、光电性质、磁性等方面表现出的独特性能.引起了人们广泛的研究兴趣.

One complex [Cd(4,4′-bipy)(2,4-Cl 2C 6H 5OCH 2COOH) 2] n has been synthesized by means of solvent method with 2,4-dichiorphenowyacetic acid and 4,4′-bipyridine(4,4′-bipy). It crystallizes in the Monoclinic space group C2/cn, with a=2.3425(3) nm, 6=1.181 00(1.5) nm, c=0.97794(13) nm, β=96.819(2)°, V=2.6863(6) nm 3, D c=1.752 g · cm -3, Z=4, F(000)=I 408. Final GooF =1.038, R 1 =0.023 8, wR 2 = 0.060 4. The crystal structure shows that the cadmium ion is coordinated with four oxygen atoms from four 2,4-dichlorphenoxyacetic acid radical and ...