期刊论文

Yang Ying-Qun

英文

无机化学学报

1001-4861

2010

26

10

1890-1894

衡阳市科技计划项目（No.2009KJ26） 湖南省重点建设学科项目资助

本校为第一且通讯机构

One new complex Cd2(2,4-DAA)4(2,2′-bipy) 2 with 2,4-dichlorophenoxy acetic acid (2,4-DAA) and 2,2′ - bipyridine (2,2′-bipy) as ligands has been synthesized and characterized. Crystal data for this complex are as follows: monoclinic, space group P1̄, α= 1.049 9(2) nm, 6 = 1.094 2(2) nm, c = 1.185 7(2) nm, α=96.70(3)°, β=105.20(3)°, γ= 91.75(3)°, V=1.303 0(5) nm3, Dc= 1.806 g · cm-3, Z=2, μ(Mo K α)=1.295 mm-1, F(000)=704, final discrepancy factors R1 =0.042 1, wR2 = 0.102 1. In the crystal, two neighboring Cd(II) ions are bridged by...

The study of carboxyl complexes has drawn great interests,mainly because of their intriguing variety of architectures and topologies as well as potential applications in many fields,such as functional materials,bioche...