期刊论文

Li Chang-Hong

中文

无机化学学报

1001-4861

2010

26

6

1129-1132

湖南省科技厅项目

本校为其他机构

近年来,人们对锰配合物的研究引起极大兴趣,这主要归因于锰的配合物有其生物功能。生物体内的过氧氢化酶、过氧歧化酶和放氧复合物,这三种酶的作用都涉及锰离子,锰离子参与了生物体内的氧。

One novel binucear manganese(II) complex Mn2(phen)2 ·(o-ABA)4 · (H2O)2 with o-acetamidobenzoic acid (o-ABA) and 1,10-phenanthroline (phen) has been synthesized and characterized. Crystal data for this complex: monoclinic, space group P21/c, a=0.80226(16) nm, b=2.6186(5) nm, c=1.281 6(3) nm, β=95.83(3)°, V=2.678 5(9) nm3, Dc=1.511 g·cm-3, D=2, F(000) = 1 260, Final GooF=1.084, R 1=0.057 8, wR2=0.118 9. The crystal structure shows that two neighboring manganese (II) ions are linked together by two bridging o-acetamidobenzoic acid, forming a ...