期刊论文

Yang Ying-Qun

英文

无机化学学报

1001-4861

2010

26

3

546-550

衡阳市科技计划项目(No.2009KJ26) 湖南省重点建设学科资助项目

本校为第一且通讯机构

The complex [Tb2(ClC6H4COO) 6(2,2′-bipy)2] (ClC6H4COOH) -(H2O)with m-chlorobenzoic acid and 2,2′-bipy-ridine as ligands has been synthesized by means of hydrothermal way. Crystal data for this complex are as follows: monoclinic, space group P1̄, a=1.143 9(4) nm, b = 1.211 6(4) nm, c=1.419 9(5) nm, α=103.600(6)°, β=95.382(3)°, γ= 99.506(4)°, V=1.868 4(10) nm3, Dc=1.692 g-cm-3, Z=2μ(Mo Kα)=2.236 mm-1, F(000)=943, final discrepancy factors Ri=0.052 0, wR2=0.l 18 6. In the crystal, two neighboring Tb(III) ions are bridged by four m-chlor...

The complex[Tb_2(ClC_6H_4COO)_6(2,2'-bipy)_2]·(ClC_6H_4COOH)·(H_2O)with m-chlorobenzoic acid and 2,2'-bipy -ridine as ligands has been synthesized by means of hydrothermal way.Crystal data for this complex are as follows: monoclinic,space group P1,a=1.143 9(4) nm,6=1.211 6(4) nm,c=1.419 9(5) nm,α= 103.600(6)°,β=95.382(3)°,γ= 99.506(4)°,V=1.8684(10)nm~3,D_c=1.692 g·cm~(-3),Z=2,μ(Mo Kα)=2.236 mm~(-1),F(000)=943,final discrepancy factors R_1=0.052 0,wR_2=0.118 6.In the crystal,two neighboring Tb(Ⅲ) ions are bridged by four m-chlorobenz...