期刊论文

Yang Ying-Qun

英文

无机化学学报

1001-4861

2010

26

3

546-550

衡阳市科技计划项目(No.2009KJ26) 湖南省重点建设学科资助项目

本校为第一且通讯机构

The complex [Tb(2)(ClC(6)H(4)COO)(6)(2,2'-bipy)(2)]center dot(ClC(6)H(4)COOH)center dot(H(2)O)with m-chlorobenzoic acid and 2,2'-bipy-ridine as ligands has been synthesized by means of hydrothermal way. Crystal data for this complex are as follows: monoclinic, space group P (1) over bar, a=1.143 9(4) nm, b=1.211 6(4) nm, c=1.419 9(5) nm, alpha=103.600(6)degrees, beta=95.382(3)degrees, gamma=99.506(4)degrees, V=1.8684(10) nm(3), D(c)=1.692 g.cm(-3), Z=2,mu(Mo K alpha)=2.236 mm(-1), F(000)=943, final discrepancy factors R(1)=0.052 0, wR(2)=0.118 6. In the crystal, two neighboring Tb(III) ions ar...

The complex[Tb_2(ClC_6H_4COO)_6(2,2'-bipy)_2]·(ClC_6H_4COOH)·(H_2O)with m-chlorobenzoic acid and 2,2'-bipy -ridine as ligands has been synthesized by means of hydrothermal way.Crystal data for this complex are as follows: monoclinic,space group P1,a=1.143 9(4) nm,6=1.211 6(4) nm,c=1.419 9(5) nm,α= 103.600(6)°,β=95.382(3)°,γ= 99.506(4)°,V=1.8684(10)nm~3,D_c=1.692 g·cm~(-3),Z=2,μ(Mo Kα)=2.236 mm~(-1),F(000)=943,final discrepancy factors R_1=0.052 0,wR_2=0.118 6.In the crystal,two neighboring Tb(Ⅲ) ions are bridged by four m-chlorobenz...