期刊论文

Li Wei

中文

无机化学学报

1001-4861

2010

26

1

166-170

湖南省科技厅项目（No.2008FJ3023,2009FJ3101）； 湖南省重点建设学科资助项目；

本校为第一且通讯机构

羧酸因其具有多样的配位方式、羧基氧原子易参与形成氢键以及本身能减缓抗衡离子效应的负电性而被广泛应用于配合物的合成中~[1-4].目前,研究主要集中于苯甲酸及其衍生物构筑的配合物,而其中以吸电子基团取代的衍生物为配体建构的配合物多集中于卤素~[5-6]、硝基~[7-8]、氰基~[9-10]等.

One novel binuclear cadmimum(II) Complex [Cd-2(phen)(2)(C15H11O3)(4)]center dot(H2O) with o-methylbenzoyl-benzoic acid and 1,10-phenanthroline(phen) has been synthesized by means of hydrothermal way and characterized. It was characterized as crystallizing in the Triclinic space group P (1) over bar with a=1.1155(2)nm, b=1.2069(2)nm, c=1.4355(3) nm, alpha=99.79(3)degrees, beta=111.27(3)degrees, gamma=98.17(3)degrees, V=1.7305(6) nm(3), D-c=1.514 g.cm(-3), Z=1, F(000)=804. Final GooF=1.060, R-1=0.024 7, wR(2)=0.063 2. The crystal structure shows that the cadmium ion is coordinated with four oxyg...