The tri(o-chlorobenzyl)tin cinnamate was synthesized by microwave assisted solid-state synthesis structure has been determined by X-ray single crystal diffraction. The crystal belongs to triclinic with s group P1̄, a=0.974 91(3) nm, b =1.096 57(3) nm, c = 1.485 91(4) nm, α=104.115 0(10)° β=90.241 0(10), γ= 111.715 0(10)°, V=1.423 35(7) nm3, Z=2, Dc=1.499 g-cm-3, μ(Mo Kα)= 12.04 cm-1, F(000)=644, R1=0.024 9, wR2=0.083 6. In the complex, the tin atom has a distorted tetrahedral geometry. The study on title complex been performed, with qua...