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Hydrothermal Synthesis, crystal structure, fluorescence and electrochemical properties of allo-bisbridge binnclear copper(II) complex based on methoxybenzoic acid and l, 10-phenanthroline

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成果类型:
期刊论文
作者:
Chen Z.-M.;Zou J.-L.;Yang Y.-Q.;Kuang D.-Z.;Wang J.-Q.;...
通讯作者:
Kuang, D.-Z.
作者机构:
[Chen Z.-M.; Kuang D.-Z.; Yang Y.-Q.; Chen M.-S.; Zhang F.-X.; Wang J.-Q.; Zou J.-L.] Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008, China
通讯机构:
[Kuang, D.-Z.] D
Department of Chemistry and Materials Science, , Hengyang, Hunan 421008, China
语种:
英文
关键词:
Allo-bisbridge;Binnclear copper(II) complex;Crystal structure;Electrochemical property;Luminescence property
期刊:
无机化学学报
ISSN:
1001-4861
年:
2011
卷:
27
期:
11
页码:
2167-2171
机构署名:
本校为第一且通讯机构
院系归属:
化学与材料科学学院
摘要:
The novel complex [Cu2(μ-OH)(Mba)(Phen)2]·(ClO4)2 has been hydrothermally synthesized by Hmba and Phen with copper(II), where Hmba=methoxybenzoic acid and Phen=1,10-phenanthroline. The crystal structure of the complex has been determined by X-ray diffraction. The crystal belong to monoclinic system, space group P21/n The cell parameters are: a=1.149 6(2)nm, b = 1,623 9(3) nm, c = 1.740 4(4) nm, β=106.52(3)°, V=3.115 1(1) nm3, Z=4, μ(Mo K(α)=16.14 cm-1, F (000)=1 728, R1=0.0296, wR2=0.075 7 (I>2σ(I)). The two centric copper(II) ions ar...

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