期刊论文

Chen Man-Sheng

英文

无机化学学报

1001-4861

2012

28

7

1525-1529

湖南省教育厅创新平台开放基金（N0.11K009）资助项目.

本校为第一且通讯机构

A new 3d-4f coordination polymer {[CuTb 2(INAIP) 3(HCOO)(H 2O) 3] · 3H 2O} n (1) was obtained by solvothermal assembly of CuCl 2·H 2O and Tb(NO 3) 3·6H 2O with the H 2INAIP (5-(isonicotinamido)isophthalic acid) ligand. Complex l crystallizes in triclinic, space group P1̄ with a=1.088 79(16) nm, b = 1.518 5(2) nm, c = 1.565 3(2) nm, D=2.338 1(6) nm 3, Z=2, C 43H 37CuTb 2N 6O 23,M r=1387.17, D c=1.970 g·cm -3,μ=3.538 mm -1, F(000)=1360,R int=0.021 2, R=0.058 9, wR =0.129 2. Single-crystal X-ray diffraction analysis revealed that each INAIP ...

由溶剂热法合成了一种新型混核化合物{[CuTb2(INAIP)3(HCOO)(H22O)3]· 3H2O}n(1)(INAIP=异烟酰胺吡啶基异酞酸根),并对其进行了元素分析、IR及X-射线衍射法表征.晶体结构研究表明:配合物1属于三斜晶系,P(1)空间群.配合物1是由配体异烟酰胺吡啶基异酞酸连接而成的三维二重贯穿结构.荧光测试研究表明配合物1具有典型的稀土铽离子绿色荧光.