期刊论文

Kuang Dai-Zhi

中文

无机化学学报

1001-4861

2014

30

6

1267-1272

10.11862/CJIC.2014.116

13JJ3112:湖南省自然科学基金 2013TZ2025:湖南省科技计划 13K105:湖南省高等学校创新平台开放基金 12C0537:国家自然科学基金 2011KG56,2012KJ30:衡阳市科技计划 12XT02:衡阳师范学院协同创新中心培育项目 2012:衡阳师范学院青年骨干教师培养计划

本校为第一且通讯机构

甲醇中三环己基氢氧化锡分别与呋喃-2-甲酸、2,4,6-三甲基苯甲酸反应,合成了2个三环己基锡芳香羧酸酯 Cy_3SnO_2CC_4H_3O(1)和Cy_3SnO_2CC_6H_2Me_3(2)(Cy为环己基)。通过IR、~1H和~(13)C NMR、元素分析及X-射线单晶衍射表征结构。1和2均属单斜晶系,配合物1空间群P2_1,晶体学参数:a=0.823 04(2) nm,b=1.111 19(3) nm,c=1.283 90(3) nm,β=101.090(2)°,Z=2,V= 1.152 27(5) nm~3,D_c=1.381 g·cm~(-3),μ(Mo Kα)=1.127 mm~(-1),F(000)=496,R_1=0.052 9,wR_2=0.138 7。配合物2空间群P2_1/c,晶体学参数:a=0.999 62(2) nm,b=1.415 97(2) nm,c=1.973 59(3) nm,β=94.042 0(10)°,Z=4,V=2.786 53(8) ...

Two tricyclohexyltin aromatic carboxylates Cy3SnO2CC4H3O(1) and Cy3SnO2CC6H2Me3 (2) were synthesized by the reactions of 2-furancarboxylic acid and 2,4,6-trimethylbenzoic acid with tricyclohexyltin hydroxide, respectively. The two complexes were characterized by IR, 1H and 13C NMR, elemental analysis and X-ray crystal diffraction. The crystal of complex 1 belongs to monoclinic system, space group P21 a=0.823 04(2) nm, b=1.111 19(3) nm, c=1.283 90(3) nm, β= 101.090(2) °, Z=2, V=1.152 27(5) nm3, Dc=1.381 g · cm−3, μ(Mo Kα)=1.127 mm−1, F(00...