Four bis(tricyclohexyltin)pyridinedicarboxylates, {[(2,6-Hpydc)SnCy3]·Me}n(1), [(2,6-pydc)Sn2Cy6(H2O)]·Ph H(2), [(3,5-pydc)Sn2Cy6(MeOH)]·MeOH(3) and [(3,5-pydc)Sn2Cy6(H2O)]·EtOH(4), have been prepared by the microwave-assisted solvothermal reaction of tricyclohexyltin hydroxide with 2,6-H2pydc and 3,5-H2pydc(H2pydc=pyridinedicarboxylic acid), respectively. Compounds 1~4 have been characterized by elemental, IR,(1H,13C and119Sn) NMR and single crystal X-ray diffraction analyses. The distorted tetrahedral and trigonal bipyramid geometry is fo...