期刊论文

中文

无机化学学报

1001-4861

2022

38

6

1171-1179

10.11862/CJIC.2022.105

功能金属有机化合物湖南省重点实验室资助；

本校为第一机构

采用间苯二（取代水杨醛酰腙）（H4L）与R3~2SnOH溶剂热反应，或间苯二甲酰肼、3-叔丁基水杨醛和三环己基氢氧化锡一锅溶剂热法反应，合成了4个新的有机锡配合物（SnR~2）2L （1～4），其中，H4L=m-Ph（CONH—N=CH（o-OH）Ph R~1）2;R~1=NEt2,R~2=Ph （1）;R~1=3,5-di-tert-butyl=3,5-t-2Bu,R~2=Ph （2）;R~1=3,5-t-2Bu,R~2=Cy （3）;R~1=3-tert-butyl=3-t-Bu,R~2=Cy （4）。经元素分析、红外光谱和(~1H、13C、119Sn)核磁共振谱表征，并用X射线衍射方法确证配合物1～4的结构。配体H4L的2个取代水杨醛酰腙链向内取向并与锡原子配位形成3个内向E型配合物1～3，取代水杨醛酰腙链向外取向并与锡原子...

Four new organotin complexes based on m - phthaloyl bis(substituted salicylaldehyde acylhydrazone) (H4L), (SnR2)(2)L (1-4), were synthesized by solvothermal reaction of H4L with (R3SnOH)-Sn-2, or one-pot solvothermal reaction of m - phthaloyl hydrazide, 3 - tert - butyl salicylaldehyde, and tricyclohexyltin hydroxide, where H4L=m - Ph (CONH-N=CH(o-OH)PhR1)(2); R-1= NEt2, R-2=Ph (1); R-1=3,5-di-tert-butyl=3,5-t-2Bu, R-2=Ph (2); R-1=3,5-t-2Bu, R-2=Cy (3); R-1=3-tert-butyl=3-t-Bu, R-2=Cy (4). And they were characterized by elemental analysis, IR, and (H-1, C-13, and Sn-119) NMR. The structures of...